Synthesis, characterization, and thermomechanical properties of liquid crystalline epoxy resin containing ketone mesogen

2016 ◽  
Vol 57 (4) ◽  
pp. 424-431 ◽  
Author(s):  
Yi-Sheng Lin ◽  
Steve Lien-Chung Hsu ◽  
Tsung-Han Ho ◽  
Shi-Shiun Cheng ◽  
Yu-Hsiang Hsiao
2018 ◽  
Vol 39 (S4) ◽  
pp. E2573-E2583 ◽  
Author(s):  
Beata Mossety-Leszczak ◽  
Maciej Kisiel ◽  
Piotr Szałański ◽  
Magdalena Włodarska ◽  
Urszula Szeluga ◽  
...  

2019 ◽  
Vol 46 (10) ◽  
pp. 1467-1477 ◽  
Author(s):  
Zirui Lin ◽  
Yuehua Cong ◽  
Baoyan Zhang ◽  
Haozhou Huang

2010 ◽  
Vol 428-429 ◽  
pp. 71-74 ◽  
Author(s):  
Jun Gang Gao ◽  
Cai Yun Zhang ◽  
Li Huo ◽  
Yuan Yuan Zhang

A liquid crystalline epoxy resin of p-biphenylene di-4-(2,3-epoxypropyloxy)benzoate (p-BDEPB) was synthesized from allyl bromide, 4-hydroxy ethyl benzoate and 4,4-dihydroxybiphenyl. Its structure and liquid crystalline behavior were characterized by DSC, 1H-NMR, FTIR, POM and XRD. The results are shown that this compound is smectic liquid crystalline.The melting point of p-BDEPB is 210 oC and clearing point is over 300 oC, the epoxy value is 0.312 mol/100g. The average curing Ea of p-BDEPB/3-methyl-tetrahydrophthalic anhydride (MeTHPA) system is 97.2kJ/mol. The gel point of cured-system Tgel is 89.0 oC, curing temperature Tcu is 132.5 oC and finishing temperature Tf is 146.5 oC. The curing reaction can be described by the autocatalytic Šesták-Berggren (S-B) equation, the two reaction orders m and n is 0.23 and 0.74, respectively.


2001 ◽  
Vol 15 (13) ◽  
pp. 1635-1654 ◽  
Author(s):  
C. Carfagna ◽  
V. Ambrogi ◽  
G. Malucelli ◽  
M. Giamberini

1995 ◽  
Vol 35 (2) ◽  
pp. 137-143 ◽  
Author(s):  
C. Carfagna ◽  
E. Amendola ◽  
M. Giamberini ◽  
G. Mensitieri ◽  
M. A. Del Nobile ◽  
...  

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