Mechanical Properties and Morphology Studies of Thermosets from a Liquid-Crystalline Epoxy Resin with Biphenol and Aromatic Ester Groups

2010 ◽  
Vol 296 (1) ◽  
pp. 83-91 ◽  
Author(s):  
Yin-Ling Liu ◽  
Zhi-Qi Cai ◽  
Wei-Cheng Wang ◽  
Xiufang Wen ◽  
Pihui Pi ◽  
...  
2002 ◽  
Vol 23 (4) ◽  
pp. 564-573 ◽  
Author(s):  
Prakaipetch Punchaipetch ◽  
Nandika Anne D'Souza ◽  
Witold Brostow ◽  
James T. Smith

2010 ◽  
Vol 67 (1) ◽  
pp. 57-66 ◽  
Author(s):  
Yin-Ling Liu ◽  
Zhi-Qi Cai ◽  
Xiufang Wen ◽  
Pihui Pi ◽  
Dafeng Zheng ◽  
...  

2011 ◽  
Vol 513 (1-2) ◽  
pp. 88-93 ◽  
Author(s):  
Yin-Ling Liu ◽  
Zhi-Qi Cai ◽  
Xiufang Wen ◽  
Pihui Pi ◽  
Dafeng Zheng ◽  
...  

2015 ◽  
Vol 132 (40) ◽  
pp. n/a-n/a ◽  
Author(s):  
Huilong Guo ◽  
Yinwen Li ◽  
Jian Zheng ◽  
Jianqun Gan ◽  
Liyan Liang ◽  
...  

2019 ◽  
Vol 46 (10) ◽  
pp. 1467-1477 ◽  
Author(s):  
Zirui Lin ◽  
Yuehua Cong ◽  
Baoyan Zhang ◽  
Haozhou Huang

2010 ◽  
Vol 428-429 ◽  
pp. 71-74 ◽  
Author(s):  
Jun Gang Gao ◽  
Cai Yun Zhang ◽  
Li Huo ◽  
Yuan Yuan Zhang

A liquid crystalline epoxy resin of p-biphenylene di-4-(2,3-epoxypropyloxy)benzoate (p-BDEPB) was synthesized from allyl bromide, 4-hydroxy ethyl benzoate and 4,4-dihydroxybiphenyl. Its structure and liquid crystalline behavior were characterized by DSC, 1H-NMR, FTIR, POM and XRD. The results are shown that this compound is smectic liquid crystalline.The melting point of p-BDEPB is 210 oC and clearing point is over 300 oC, the epoxy value is 0.312 mol/100g. The average curing Ea of p-BDEPB/3-methyl-tetrahydrophthalic anhydride (MeTHPA) system is 97.2kJ/mol. The gel point of cured-system Tgel is 89.0 oC, curing temperature Tcu is 132.5 oC and finishing temperature Tf is 146.5 oC. The curing reaction can be described by the autocatalytic Šesták-Berggren (S-B) equation, the two reaction orders m and n is 0.23 and 0.74, respectively.


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