Kinetics of oxidation of acidic amino acids and their monoamides byN-chloroarylsulphonamides in aqueous acidic medium

2004 ◽  
Vol 17 (10) ◽  
pp. 848-864 ◽  
Author(s):  
B. Thimme Gowda ◽  
Mahesha Shetty
Keyword(s):  
Amino Acids ◽  
Acidic Medium ◽  
Kinetics Of Oxidation ◽  
Acidic Amino Acids ◽  
Kinetics Of ◽  
Aqueous Acidic Medium

scholarly journals Kinetics and Mechanism of Oxidation of Glutamic Acid byN-Bromophthalimide in Aqueous Acidic Medium

2011 ◽  
Vol 8 (4) ◽  
pp. 1472-1477
Author(s):  
N. M. I. Alhaji ◽  
S. Sofiya Lawrence Mary
Keyword(s):  
Dielectric Constant ◽  
Ionic Strength ◽  
Glutamic Acid ◽  
Acidic Medium ◽  
Reaction Medium ◽  
Kinetics Of Oxidation ◽  
First Order ◽  
Mechanism Of Oxidation ◽  
Kinetics Of ◽  
Aqueous Acidic Medium

The kinetics of oxidation of glutamic acid (Glu) withN-bromophthalimide (NBP) was studied in perchloric acid medium at 30°C by potentiometric method. The reaction is first order each in NBP and glutamic acid and is negative fractional order in [H+]. Addition of KBr or the reaction product, phthalimide had no effect on the rate. Similarly variation of ionic strength of the medium did not affect the rate of the reaction. Also the rate increased with decrease in dielectric constant of the reaction medium. The thermodynamic parameters were computed from Arrhenius and Eyring plots. A suitable mechanism consistent with the kinetic results has been proposed.

Kinetics of oxidation of amino acids by chloramine T. A reinvestigation

1985 ◽  
pp. 1507 ◽  
Author(s):  
M. Shanmugam Ramachandran ◽  
T. Subburamiyer Vivekanandam ◽  
Rajarathinam Nithyanandhan
Keyword(s):  
Amino Acids ◽  
Kinetics Of Oxidation ◽  
Chloramine T ◽  
Kinetics Of

Kinetics of oxidation of amino acids by alkaline hexacyanoferrate(III)

1990 ◽  
Vol 3 (12) ◽  
pp. 799-802 ◽  
Author(s):  
Didcy Laloo ◽  
Mahendra K. Mahanti
Keyword(s):  
Amino Acids ◽  
Kinetics Of Oxidation ◽  
Kinetics Of
Sign in / Sign up

Export Citation Format

Share Document