2,4,6-Tribromophenyl acrylate-co-glycidyl methacrylate polymers: Synthesis, characterization, and reactivity ratios

1992 ◽  
Vol 30 (10) ◽  
pp. 2165-2172 ◽  
Author(s):  
T. Narasimhaswamy ◽  
S. C. Sumathi ◽  
B. S. R. Reddy
Keyword(s):  
Glycidyl Methacrylate ◽  
Reactivity Ratios ◽  
Methacrylate Polymers

Copolymerization of Glycidyl Methacrylate and 1,1,1,3,3,3-Hexafluoroisopropyl Acrylate

2021 ◽  
Vol 899 ◽  
pp. 387-391
Author(s):  
Alexandra O. Grigoreva ◽  
Kseniia Tarankova ◽  
Sergey D. Zaitsev
Keyword(s):  
Glycidyl Methacrylate ◽  
Molar Mass ◽  
Chain Transfer ◽  
Good Control ◽  
Chain Transfer Agent ◽  
Polymeric Chain ◽  
Reactivity Ratios ◽  
Reversible Addition

The copolymerization of 1,1,1,3,3,3-hexafluoroisopropyl acrylate (HFIPA) and glycidyl methacrylate via reversible addition-fragmentation chain transfer (RAFT) process was investigated. 2-cyano-2-propyl dodecyl trithiocarbonate (CPDT) was used as chain transfer agent. It is turned out that CPDT and polymeric chain transfer agent obtained based on HFIPA and CPDT provide a good control over molar mass characteristic of copolymers (Đ = 1.05). Reactivity ratios were found to be r1(GMA) = 1.57 and r2(HFIPA) = 0.05 by Fineman–Ross model.

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