scholarly journals Synthesis and Characterization of Azido Esters as Green Energetic Plasticizers

Author(s):  
Jovica Nešić ◽  
Ilija N. Cvijetić ◽  
Jovica Bogdanov ◽  
Aleksandar Marinković
2021 ◽  
Vol 21 (7) ◽  
pp. 4110-4115
Author(s):  
Yechen Shen ◽  
Younghwan Kwon

Two reactive energetic plasticizers, 3-((2,2-dinitropropoxy)methoxy)prop-1-yne and 4-((2,2-dinitropropoxy)methoxy)but-1-yne which can react with an azido-containing poly(glycidyl azide-co-tetramethylene glycol) prepolymer by cupper-free 1,3-dipolor cycloaddition (“Click”) reaction, were synthesized and characterized, in order to investigate their plasticizing performance and catalyst-free 1,3-dipolar cycloaddition reactivity on energetic polyurethane binders. Two reactive energetic plasticizers showed better plasticizing performance than commercial energetic plasticizers. In the reactivity point of view, 3-((2,2-dinitropropoxy)methoxy)prop-1-yne exhibited higher Click reactivity than 4-((2,2-dinitropropoxy)methoxy)but-1-yne. Two synthesized plasticizers were found to fulfill the requirements for use as reactive energetic plasticizers.


FirePhysChem ◽  
2021 ◽  
Author(s):  
Qi Xue ◽  
Fuqiang Bi ◽  
Junlin Zhang ◽  
Jiarong Zhang ◽  
Bozhou Wang ◽  
...  

2020 ◽  
Vol 17 (3) ◽  
pp. 323-343
Author(s):  
Fariborz Atabaki ◽  
Naser Noorollahy Bastam ◽  
Hamid Reza Hafizi-Atabak ◽  
Mehran Radvar ◽  
Shahrzad Jahangiri

1996 ◽  
Vol 61 (10) ◽  
pp. 3572-3572
Author(s):  
Lawrence T. Scott ◽  
Atena Necula

Sign in / Sign up

Export Citation Format

Share Document