The Charge Storage Mechanism of MnCO 3 in Aqueous Electrolytes

2020 ◽  
Vol 5 (17) ◽  
pp. 5316-5322
Author(s):  
Vishnu Vardhan Palem ◽  
Mustapha Balarabe Idris ◽  
Thiruvenkatam Subramaniam ◽  
Devaraj Sappani
Keyword(s):  
Charge Storage ◽  
Aqueous Electrolytes ◽  
Storage Mechanism ◽  
Charge Storage Mechanism

scholarly journals The Role of Al3+-Based Aqueous Electrolytes in the Charge Storage Mechanism of MnOx Cathodes

2020 ◽  
Author(s):  
Véronique Balland ◽  
Mickaël Mateos ◽  
Kenneth D. Harris ◽  
Benoit Limoges
Keyword(s):  
Manganese Oxide ◽  
Critical Analysis ◽  
Charge Storage ◽  
Aqueous Electrolytes ◽  
Storage Mechanism ◽  
Main Charge ◽  
Charge Storage Mechanism ◽  
The Subject

<p>Rechargeable aqueous aluminium batteries are the subject of growing interest, but the charge storage mechanisms at manganese oxide-based cathodes remain poorly understood with as many mechanisms as studies. Here, we use an original <i>in situ</i> spectroelectrochemical methodology to unambiguously demonstrate that the reversible proton-coupled MnO<sub>2</sub>-to-Mn<sup>2+</sup> conversion is the main charge storage mechanism occurring at MnO<sub>2</sub> cathodes over a range of slightly acidic Al<sup>3+</sup>-based aqueous electrolytes. In Zn/MnO<sub>2</sub> assemblies, this mechanism is associated with high gravimetric capacity and discharge potentials, up to 560 mAh·g<sup>-1</sup> and 1.76 V respectively, attractive efficiencies (<i>CE</i> > 98.5 % and <i>EE</i> > 80%) and excellent cyclability (> 750 cycles at 10 A·g<sup>-1</sup>). Finally, we conducted a critical analysis of the data previously published on MnO<sub>x</sub> cathodes in Al<sup>3+</sup>-based aqueous electrolytes to conclude on a universal charge storage mechanism, <i>i.e.</i>, the reversible electrodissolution/electrodeposition of MnO<sub>2</sub>.<i></i></p>

A proton-hopping charge storage mechanism of ionic one-dimensional coordination polymers for high-performance supercapacitors

2017 ◽  
Vol 53 (86) ◽  
pp. 11786-11789 ◽  
Author(s):  
Nutthaphon Phattharasupakun ◽  
Juthaporn Wutthiprom ◽  
Surasak Kaenket ◽  
Thana Maihom ◽  
Jumras Limtrakul ◽  
...  
Keyword(s):  
Coordination Polymer ◽  
Coordination Polymers ◽  
High Performance ◽  
Charge Storage ◽  
Aqueous Electrolytes ◽  
Proton Conducting ◽  
One Dimensional ◽  
Storage Mechanism ◽  
Charge Storage Mechanism

A proton-conducting coordination polymer of Zn2+ phosphate and protonated imidazole has been used as a novel supercapacitor material in aqueous electrolytes.

scholarly journals The Role of Al3+-Based Aqueous Electrolytes in the Charge Storage Mechanism of MnOx Cathodes

2020 ◽  
Author(s):  
Véronique Balland ◽  
Mickaël Mateos ◽  
Kenneth D. Harris ◽  
Benoit Limoges
Keyword(s):  
Manganese Oxide ◽  
Critical Analysis ◽  
Charge Storage ◽  
Aqueous Electrolytes ◽  
Storage Mechanism ◽  
Main Charge ◽  
Charge Storage Mechanism ◽  
The Subject

<p>Rechargeable aqueous aluminium batteries are the subject of growing interest, but the charge storage mechanisms at manganese oxide-based cathodes remain poorly understood with as many mechanisms as studies. Here, we use an original <i>in situ</i> spectroelectrochemical methodology to unambiguously demonstrate that the reversible proton-coupled MnO<sub>2</sub>-to-Mn<sup>2+</sup> conversion is the main charge storage mechanism occurring at MnO<sub>2</sub> cathodes over a range of slightly acidic Al<sup>3+</sup>-based aqueous electrolytes. In Zn/MnO<sub>2</sub> assemblies, this mechanism is associated with high gravimetric capacity and discharge potentials, up to 560 mAh·g<sup>-1</sup> and 1.76 V respectively, attractive efficiencies (<i>CE</i> > 98.5 % and <i>EE</i> > 80%) and excellent cyclability (> 750 cycles at 10 A·g<sup>-1</sup>). Finally, we conducted a critical analysis of the data previously published on MnO<sub>x</sub> cathodes in Al<sup>3+</sup>-based aqueous electrolytes to conclude on a universal charge storage mechanism, <i>i.e.</i>, the reversible electrodissolution/electrodeposition of MnO<sub>2</sub>.<i></i></p>

Charge storage mechanism and degradation of P2-type sodium transition metal oxides in aqueous electrolytes

2018 ◽  
Vol 6 (44) ◽  
pp. 22266-22276 ◽  
Author(s):  
Shelby Boyd ◽  
Rohan Dhall ◽  
James M. LeBeau ◽  
Veronica Augustyn
Keyword(s):  
Transition Metal ◽  
Metal Oxides ◽  
Transition Metal Oxides ◽  
Structural Changes ◽  
Charge Storage ◽  
Aqueous Electrolytes ◽  
Storage Mechanism ◽  
Charge Storage Mechanism

P2-type sodium transition metal oxides undergo water-driven structural changes that strongly affect electrochemical charge storage in aqueous electrolytes.

scholarly journals Enhanced Charge Storage Mechanism and Long-Term Cycling Stability in Diamondized Titania Nanocomposite Supercapacitors Operating in Aqueous Electrolytes

2020 ◽  
Vol 124 (29) ◽  
pp. 15698-15712 ◽  
Author(s):  
Robert Bogdanowicz ◽  
Anna Dettlaff ◽  
Franciszek Skiba ◽  
Konrad Trzcinski ◽  
Mariusz Szkoda ◽  
...  
Keyword(s):  
Cycling Stability ◽  
Charge Storage ◽  
Aqueous Electrolytes ◽  
Storage Mechanism ◽  
Charge Storage Mechanism

Effect of Structural Ordering on the Charge Storage Mechanism of p-Type Organic Electrode Materials

2021 ◽  
Vol 13 (6) ◽  
pp. 7135-7141 ◽  
Author(s):  
Brian M. Peterson ◽  
Cara N. Gannett ◽  
Luis Melecio-Zambrano ◽  
Brett P. Fors ◽  
Héctor Abruña
Keyword(s):  
Electrode Materials ◽  
Charge Storage ◽  
Structural Ordering ◽  
Storage Mechanism ◽  
Organic Electrode ◽  
Charge Storage Mechanism ◽  
P Type

Unraveling the different charge storage mechanism in T and H phases of MoS2

2016 ◽  
Vol 217 ◽  
pp. 1-8 ◽  
Author(s):  
Bao Zhang ◽  
Xiao Ji ◽  
Kui Xu ◽  
Chi Chen ◽  
Xiong Xiong ◽  
...  
Keyword(s):  
Charge Storage ◽  
Storage Mechanism ◽  
Charge Storage Mechanism

Understanding and Calibration of Charge Storage Mechanism in Cyclic Voltammetry Curves

2021 ◽  
Author(s):  
Xiangjun Pu ◽  
Dong Zhao ◽  
Chenglong Fu ◽  
Zhongxue Chen ◽  
Shunan Cao ◽  
...  
Keyword(s):  
Cyclic Voltammetry ◽  
Charge Storage ◽  
Storage Mechanism ◽  
Charge Storage Mechanism

scholarly journals Na2.4Al0.4Mn2.6O7 anionic redox cathode material for sodium ion batteries- a combined experimental and theoretical approach to elucidate its charge storage mechanism

2022 ◽  
Author(s):  
Cindy Soares ◽  
Begoña Silvan ◽  
Yong-Seok Choi ◽  
Veronica Celorrio ◽  
Giannantonio Cibin ◽  
...  
Keyword(s):  
Cathode Material ◽  
Theoretical Approach ◽  
High Performance ◽  
Sodium Ion ◽  
Charge Storage ◽  
Sodium Ion Batteries ◽  
Storage Mechanism ◽  
Charge Storage Mechanism

Here we report the synthesis via ceramic methods of the high-performance Mn-rich Na2.4Al0.4Mn2.6O7 oxygen-redox cathode material for Na-ion batteries which we use as a testbed material to study the effects...

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