Asymmetric Hydrogenation of Quinoline Derivatives Catalyzed by Cationic Transition Metal Complexes of Chiral Diamine Ligands: Scope, Mechanism and Catalyst Recycling

2016 ◽  
Vol 16 (6) ◽  
pp. 2697-2711 ◽  
Author(s):  
Yi-Er Luo ◽  
Yan-Mei He ◽  
Qing-Hua Fan
Keyword(s):  
Transition Metal ◽  
Metal Complexes ◽  
Transition Metal Complexes ◽  
Asymmetric Hydrogenation ◽  
Quinoline Derivatives ◽  
Catalyst Recycling ◽  
Chiral Diamine ◽  
Diamine Ligands

Asymmetric hydrogenation catalyzed by first-row transition metal complexes

2021 ◽  
Author(s):  
Jialin Wen ◽  
Fangyuan Wang ◽  
Xumu Zhang
Keyword(s):  
Transition Metal ◽  
Metal Complexes ◽  
Transition Metal Complexes ◽  
Reaction Mechanisms ◽  
Asymmetric Hydrogenation ◽  
Transfer Hydrogenation

This review focuses on asymmetric direct and transfer hydrogenation with first-row transition metal complexes. The reaction mechanisms and the models of enantiomeric induction were summarized and emphasized.

Mechanochemical changes on cyclometalated Ir(iii) acyclic carbene complexes – design and tuning of luminescent mechanochromic transition metal complexes

2020 ◽  
Vol 7 (3) ◽  
pp. 786-794 ◽  
Author(s):  
Jingqi Han ◽  
Kin-Man Tang ◽  
Shun-Cheung Cheng ◽  
Chi-On Ng ◽  
Yuen-Kiu Chun ◽  
...  
Keyword(s):  
Transition Metal ◽  
Metal Complexes ◽  
Transition Metal Complexes ◽  
Carbene Complexes ◽  
New Class

A new class of luminescent cyclometalated Ir(iii) complexes with readily tunable mechanochromic properties derived from the mechanically induced trans-to-cis isomerization have been developed.

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