Synthesis, Crystal Structures and Properties of Ni(NCS)2‐3‐Cyanopyridine Coordination Compounds including a Ferromagnetic Layered Compound

Four high-dimensional AgI/POM-based hybrids have been synthesized and their optical band gaps and electrochemical and fluorescence properties have been investigated.

Download Full-text

Syntheses, crystal structures, and properties of four new coordination compounds of transition metals and imidazoledicarboxylic acid derivatives

Journal of Coordination Chemistry ◽

10.1080/00958972.2011.606907 ◽

2011 ◽

Vol 64 (16) ◽

pp. 2824-2833 ◽

Cited By ~ 12

Author(s):

Da-Peng Wang ◽

Ya-Guang Chen ◽

Hui-Yuan Wang ◽

Chun-Jing Zhang ◽

Qun Tang

Keyword(s):

Transition Metals ◽

Crystal Structures ◽

Coordination Compounds ◽

Structures And Properties

Download Full-text

On the thermal decomposition pathway of coordination compounds: synthesis, crystal structures and properties of new polymorphic CuI(2-ethylpyrazine) coordination compounds

Solid State Sciences ◽

10.1016/j.solidstatesciences.2003.09.002 ◽

2003 ◽

Vol 5 (10) ◽

pp. 1343-1357 ◽

Cited By ~ 19

Author(s):

Christian Näther ◽

Inke Jeß ◽

Nicolai Lehnert ◽

Dirk Hinz-Hübner

Keyword(s):

Thermal Decomposition ◽

Crystal Structures ◽

Coordination Compounds ◽

Structures And Properties ◽

Decomposition Pathway

Download Full-text

Cd(II) and Zn(II) thiocyanate coordination compounds with 3-ethylpyridine: synthesis, crystal structures and properties

Zeitschrift für Naturforschung B ◽

10.1515/znb-2017-0186 ◽

2018 ◽

Vol 73 (2) ◽

pp. 115-123 ◽

Cited By ~ 2

Author(s):

Tristan Neumann ◽

Inke Jess ◽

Cesar dos Santos Cunha ◽

Huayna Terraschke ◽

Christian Näther

Keyword(s):

Crystal Structures ◽

Spectral Range ◽

Pure State ◽

Coordination Compounds ◽

Metal Cations ◽

Structures And Properties ◽

Anionic Ligands

AbstractReaction of Cd(NCS)2 and Zn(NCS)2 with 3-ethylpyridine leads to the formation of compounds of compositions M(NCS)2(3-ethylpyridine)4 (M=Cd, 1-Cd; Zn, 1-Zn) and M(NCS)2(3-ethylpyridine)2 (M=Cd, 2-Cd; Zn, 2-Zn). 1-Cd and 1-Zn are isotypic and form discrete complexes in which the metal cations are octahedrally coordinated by two trans-coordinating N-bonded thiocyanate anions and four 3-ethylpyridine co-ligands. In 2-Cd the cations are also octahedrally coordinated but linked into chains by pairs of μ-1,3-bridging anionic ligands. 2-Zn is built up of discrete complexes, in which the Zn cation is tetrahedrally coordinated by two N-bonded thiocyanate anions and two 3-ethylpyridine co-ligands. Compounds 1-Cd, 2-Cd and 2-Zn can be prepared in a pure state, whereas 1-Zn is unstable and transforms on storage into 2-Zn. If 1-Cd and 1-Zn are heated, a transformation into 2-Cd, respectively 2-Zn is observed. Luminescence measurements reveal that 1-Cd, 2-Cd and 2-Zn emit light in the blue spectral range with maxima at, respectively, 21724, 21654 and 22055 cm−1, assigned to ligand-based luminescence.

Download Full-text