Rotational Spectrum, Structure, and Electric Dipole Moment of Bis(difluoromethyl) Ether

1998 ◽  
Vol 192 (2) ◽  
pp. 441-448 ◽  
Author(s):  
R.D. Suenram ◽  
F.J. Lovas ◽  
A.R. Hight Walker ◽  
D.A. Dixon
Keyword(s):  
Dipole Moment ◽  
Electric Dipole Moment ◽  
Electric Dipole ◽  
Rotational Spectrum ◽  
Spectrum Structure

Microwave spectrum, structure, and electric dipole moment of ArCH3OH

1989 ◽  
Vol 137 (1) ◽  
pp. 127-137 ◽  
Author(s):  
R.D Suenram ◽  
F.J Lovas ◽  
G.T Fraser ◽  
J.Z Gillies ◽  
C.W Gillies ◽  
...  
Keyword(s):  
Dipole Moment ◽  
Electric Dipole Moment ◽  
Electric Dipole ◽  
Microwave Spectrum ◽  
Spectrum Structure

ChemInform Abstract: Microwave Spectrum, Structure, and Electric Dipole Moment of Ar-CH3OH

ChemInform ◽  
1989 ◽  
Vol 20 (46) ◽  
Author(s):  
R. D. SUENRAM ◽  
F. J. LOVAS ◽  
G. T. FRASER ◽  
J. Z. GILLIES ◽  
C. W. GILLIES ◽  
...  
Keyword(s):  
Dipole Moment ◽  
Electric Dipole Moment ◽  
Electric Dipole ◽  
Microwave Spectrum ◽  
Spectrum Structure

Rotational Spectrum , Electric Dipole Moment, Quadrupole Coupling , and Partial r0- Structure of 3 -Cyanothiophene

1977 ◽  
Vol 32 (8) ◽  
pp. 890-896 ◽  
Author(s):  
J. Wiese ◽  
D. H. Sutter
Keyword(s):  
Dipole Moment ◽  
Electric Dipole Moment ◽  
Electric Dipole ◽  
Stark Effect ◽  
Quadrupole Coupling Constant ◽  
Abundant Species ◽  
Rotational Spectrum ◽  
Quadrupole Coupling ◽  
Centrifugal Distortion Constants ◽  
Ring Distortion

Abstract The microwave rotational spectrum of the most abundant species of 3-Cyanothiophene was investigated for the ground vibrational state. Rotational constants and centrifugal distortion constants are given. The electric dipole moment components μa and μb and the 14N-quadrupole coupling constant X + = X bb + X cc were determined from the Stark-effect splittings and hfs-splittings respectively. The experimental results are compared to CNDO/2 calculations and are discussed with reference to ring distortion.

Pure Rotational Spectrum and Electric Dipole Moment of CH3D

1969 ◽  
Vol 51 (11) ◽  
pp. 4873-4880 ◽  
Author(s):  
Irving Ozier ◽  
W. Ho ◽  
George Birnbaum
Keyword(s):  
Dipole Moment ◽  
Electric Dipole Moment ◽  
Electric Dipole ◽  
Rotational Spectrum

The microwave spectrum, structure, and electric dipole moment of 1,2,4-trithiolane

1984 ◽  
Vol 106 (4) ◽  
pp. 841-844 ◽  
Author(s):  
Donald G. Borseth ◽  
Kurt W. Hillig ◽  
Robert L. Kuczkowski
Keyword(s):  
Dipole Moment ◽  
Electric Dipole Moment ◽  
Electric Dipole ◽  
Microwave Spectrum ◽  
Spectrum Structure

Isotopieeffekte im Rotationsspektrum des SiS / lsotopic Effects in the Rotational Spectrum of SiS

1972 ◽  
Vol 27 (11) ◽  
pp. 1566-1570 ◽  
Author(s):  
E. Tiemann ◽  
E. Renwanz ◽  
J. Hoeft ◽  
T. Törring
Keyword(s):  
Dipole Moment ◽  
Electric Dipole Moment ◽  
Electric Dipole ◽  
Rotational Constant ◽  
Higher Order ◽  
Rotational Spectrum ◽  
Oppenheimer Approximation ◽  
Isotopic Effects

Abstract Corrections resulting from the breakdown of the Born-Oppenheimer approximation were obtained by a detailed discussion of the higher order isotopic effects of the rotational constant Y01 . This analysis yields the sign of the electric dipole moment to be positive (+SiS-) and the sign of the molecular gJ-value to be negative. The magnitude of the adiabatic correction was evaluated.

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