Hydrogenation Reactions of CO and CN Functions Using Rhodium Complexes

1983 ◽  
pp. 317-341 ◽  
Author(s):  
Bálint Heil ◽  
László Markó ◽  
Szilárd Tőrös
Keyword(s):  
Rhodium Complexes ◽  
Hydrogenation Reactions

Diphosphinoazine Rhodium(I) and Iridium(I) Complexes

2006 ◽  
Vol 71 (2) ◽  
pp. 197-206 ◽  
Author(s):  
Martin Pošta ◽  
Jan Čermák ◽  
Pavel Vojtíšek ◽  
Ivana Císařová
Keyword(s):  
Rhodium Complexes ◽  
Iridium Complexes ◽  
X Ray ◽  
First Time

The first rhodium complexes of diphosphinoazines [{RhCl(1,2-η:5,6-η-CH=CHCH2CH2CH=CHCH2CH2)}2 {μ-R2PCH2C(But)=NN=C(But)CH2PR2] (R = Ph, Cy, Pri) were prepared by cleavage of the bridge in chloro(cycloocta-1,5-diene)rhodium(I) dimer, the analogous iridium(I) complexes were also prepared for the first time. The X-ray structures of isostructural rhodium and iridium complexes with bis(dicyclohexylphosphino)pinacoloneazine were determined. Diphosphinoazine ligands in the complexes remained in (Z,Z) configuration bridging two RhCl(C8H12) units.

scholarly journals Platinum and rhodium complexes ligated by imidazolium-substituted phosphine as efficient and recyclable catalysts for hydrosilylation

RSC Advances ◽  
2019 ◽  
Vol 9 (50) ◽  
pp. 29396-29404 ◽  
Author(s):  
Magdalena Jankowska-Wajda ◽  
Olga Bartlewicz ◽  
Andrea Szpecht ◽  
Adrian Zajac ◽  
Marcin Smiglak ◽  
...  
Keyword(s):  
Rhodium Complexes ◽  
Recyclable Catalysts ◽  
High Yields

Platinum and rhodium complexes ligated by imidazolium substituted phosphine were obtained with high yields and applied as efficient catalysts.

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