Some (phenylazo)phenyl-C, N′-rhodium complexes containing trifluorophosphine

The first rhodium complexes of diphosphinoazines [{RhCl(1,2-η:5,6-η-CH=CHCH2CH2CH=CHCH2CH2)}2 {μ-R2PCH2C(But)=NN=C(But)CH2PR2] (R = Ph, Cy, Pri) were prepared by cleavage of the bridge in chloro(cycloocta-1,5-diene)rhodium(I) dimer, the analogous iridium(I) complexes were also prepared for the first time. The X-ray structures of isostructural rhodium and iridium complexes with bis(dicyclohexylphosphino)pinacoloneazine were determined. Diphosphinoazine ligands in the complexes remained in (Z,Z) configuration bridging two RhCl(C8H12) units.

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Platinum and rhodium complexes ligated by imidazolium-substituted phosphine as efficient and recyclable catalysts for hydrosilylation

RSC Advances ◽

10.1039/c9ra05948b ◽

2019 ◽

Vol 9 (50) ◽

pp. 29396-29404 ◽

Cited By ~ 4

Author(s):

Magdalena Jankowska-Wajda ◽

Olga Bartlewicz ◽

Andrea Szpecht ◽

Adrian Zajac ◽

Marcin Smiglak ◽

...

Keyword(s):

Rhodium Complexes ◽

Recyclable Catalysts ◽

High Yields

Platinum and rhodium complexes ligated by imidazolium substituted phosphine were obtained with high yields and applied as efficient catalysts.

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Synthesis of Rhodium Complexes with Chiral Diene Ligands via Diastereoselective Coordination and Their Application in the Asymmetric Insertion of Diazo Compounds into E‐H Bonds

Angewandte Chemie International Edition ◽

10.1002/anie.202105179 ◽

2021 ◽

Author(s):

Nikita M. Ankudinov ◽

Denis A. Chusov ◽

Yulia V. Nelyubina ◽

Dmitry Perekalin

Keyword(s):

Diazo Compounds ◽

Rhodium Complexes ◽

Diene Ligands

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ChemInform Abstract: CONTRIBUTIONS TO THE COMPLEX CHEMISTRY OF PHOSPHINE AND PHOSPHINE OXIDE. XXV. OBALT AND RHODIUM COMPLEXES OF PH-FUNCTIONAL MERCAPTOALKYLPHOSPHINE

Chemischer Informationsdienst ◽

10.1002/chin.197837300 ◽

1978 ◽

Vol 9 (37) ◽

Author(s):

K. ISSLEIB ◽

D. WIENBECK

Keyword(s):

Phosphine Oxide ◽

Rhodium Complexes ◽

Complex Chemistry

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ChemInform Abstract: STRUCTURAL REQUIREMENTS IN CHIRAL DIPHOSPHINE-RHODIUM COMPLEXES. X. ASYMMETRIC HOMOGENEOUS HYDROGENATION OF Z-N-ACETYLDEHYDROAMINO ACIDS AND ESTERS WITH (1R,2R)-TRANS-1,2-BIS(DIPHENYLPHOSPHINOMETHYL)CYCLOBUTANE RHODIUM(I) COMPLEXES

Chemischer Informationsdienst ◽

10.1002/chin.197809133 ◽

1978 ◽

Vol 9 (9) ◽

Author(s):

R. GLASER ◽

J. BLUMENFELD ◽

M. TWAIK

Keyword(s):

Rhodium Complexes ◽

Homogeneous Hydrogenation ◽

Structural Requirements

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ChemInform Abstract: NMR AND IR STUDIES OF THE BONDING PROPERTIES OF THE ETHYLENE-RHODIUM COMPLEXES RHCL(C2H4)(L)(L′) (L = C2H4, CO, PR3, L′ = 2,6-LUTIDINE)

Chemischer Informationsdienst ◽

10.1002/chin.197847290 ◽

1978 ◽

Vol 9 (47) ◽

Author(s):

A. MAISONNAT ◽

R. POILBLANC

Keyword(s):

Rhodium Complexes ◽

Ir Studies ◽

Bonding Properties

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Exchange and Spectroscopy of Cationic Rhodium Complexes on Hectorite

Clays and Clay Minerals ◽

10.1346/ccmn.1984.0320305 ◽

1984 ◽

Vol 32 (3) ◽

pp. 185-190 ◽

Cited By ~ 1

Author(s):

Robert A. Schoonheydt

Keyword(s):

Rhodium Complexes

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Structural and chemical properties of half-sandwich rhodium complexes supported by the bis(2-pyridyl)methane ligand

Dalton Transactions ◽

10.1039/c9dt01821b ◽

2019 ◽

Vol 48 (33) ◽

pp. 12396-12406 ◽

Cited By ~ 2

Author(s):

Davide Lionetti ◽

Victor W. Day ◽

James D. Blakemore

Keyword(s):

Chemical Properties ◽

Oxidation States ◽

Rhodium Complexes ◽

Half Sandwich ◽

And Chemical Properties

The bis(2-pyridyl)methane ligand can support [Cp*Rh] complexes (Cp* = pentamethylcyclopentadienyl) in the Rh(iii) and Rh(ii) oxidation states. Structural and reactivity studies demonstrate significant differences between these complexes and notable analogues bearing the related dimethylbis(2-pyridyl)methane ligand.

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