Energy Dispersive X-Ray Absorption Spectroscopy; A Tool for Time Resolved Structural Studies of Chemical Reactions in Solution

Author(s):  
Sofía Díaz Moreno
2005 ◽  
Vol 7 (2) ◽  
pp. 366-372 ◽  
Author(s):  
A. Rose ◽  
O. South ◽  
I. Harvey ◽  
S. Diaz-Moreno ◽  
J. R. Owen ◽  
...  

1997 ◽  
Vol 502 ◽  
Author(s):  
T. Ressler ◽  
Joe Wong ◽  
W. Metz

ABSTRACTIn addition to being an established technique for ex-situ structural studies, x-ray absorption spectroscopy (XAS) has recently been realized to be a powerful tool for in-situ time-resolved investigations in materials science. This paper describes two complementary techniques: quick-scanning EXAFS (QEXAFS) and energy-dispersive XAS (DXAS) which offer time resolution in the seconds and milliseconds range, respectively. Formation of a heterogeneous catalyst from a solid-state reaction of a precursor is presented as an example of a time-resolved XAS application.


1990 ◽  
Vol 94 (17) ◽  
pp. 6517-6519 ◽  
Author(s):  
J. W. Couves ◽  
J. M. Thomas ◽  
C. R. A. Catlow ◽  
G. N. Greaves ◽  
G. Baker ◽  
...  

2003 ◽  
Vol 5 (1) ◽  
pp. 1-5 ◽  
Author(s):  
Rachel O’Malley ◽  
Antje Vollmer ◽  
Jonathan R.I Lee ◽  
Ian Harvey ◽  
Jon Headspith ◽  
...  

2016 ◽  
Vol 23 (1) ◽  
pp. 353-368 ◽  
Author(s):  
S. Pascarelli ◽  
O. Mathon ◽  
T. Mairs ◽  
I. Kantor ◽  
G. Agostini ◽  
...  

The European Synchrotron Radiation Facility has recently made available to the user community a facility totally dedicated to Time-resolved and Extreme-conditions X-ray Absorption Spectroscopy – TEXAS. Based on an upgrade of the former energy-dispersive XAS beamline ID24, it provides a unique experimental tool combining unprecedented brilliance (up to 1014 photons s−1on a 4 µm × 4 µm FWHM spot) and detection speed for a full EXAFS spectrum (100 ps per spectrum). The science mission includes studies of processes down to the nanosecond timescale, and investigations of matter at extreme pressure (500 GPa), temperature (10000 K) and magnetic field (30 T). The core activities of the beamline are centered on new experiments dedicated to the investigation of extreme states of matter that can be maintained only for very short periods of time. Here the infrastructure, optical scheme, detection systems and sample environments used to enable the mission-critical performance are described, and examples of first results on the investigation of the electronic and local structure in melts at pressure and temperature conditions relevant to the Earth's interior and in laser-shocked matter are given.


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