Geothermal Energy as a Resource in a Hydrogen Energy Economy

1975 ◽  
pp. 57-85
Author(s):  
F. Maslan ◽  
T. J. Gordon
Keyword(s):  
Geothermal Energy ◽  
Hydrogen Energy ◽  
Energy Economy

Sustainable hydrogen energy

2007 ◽  
Author(s):  
Peter P. Edwards ◽  
Vladimir L. Kuznetsov
Keyword(s):  
Fuel Cells ◽  
Fuel Cell ◽  
Energy Supply ◽  
Fossil Fuel ◽  
Low Cost ◽  
Hydrogen Energy ◽  
The Future ◽  
Energy Economy ◽  
Fossil Fuel Energy ◽  
Carbon Based

Hydrogen is the simplest and most abundant chemical element in our universe— it is the power source that fuels the Sun and its oxide forms the oceans that cover three quarters of our planet. This ubiquitous element could be part of our urgent quest for a cleaner, greener future. Hydrogen, in association with fuel cells, is widely considered to be pivotal to our world’s energy requirements for the twenty-first century and it could potentially redefine the future global energy economy by replacing a carbon-based fossil fuel energy economy. The principal drivers behind the sustainable hydrogen energy vision are therefore: • the urgent need for a reduction in global carbon dioxide emissions; • the improvement of urban (local) air quality; • the abiding concerns about the long-term viability of fossil fuel resources and the security of our energy supply; • the creation of a new industrial and technological energy base—a base for innovation in the science and technology of a hydrogen/fuel cell energy landscape. The ultimate realization of a hydrogen-based economy could confer enormous environmental and economic benefits, together with enhanced security of energy supply. However, the transition from a carbon-based(fossil fuel) energy system to a hydrogen-based economy involves significant scientific, technological, and socio-economic barriers. These include: • low-carbon hydrogen production from clean or renewable sources; • low-cost hydrogen storage; • low-cost fuel cells; • large-scale supporting infrastructure, and • perceived safety problems. In the present chapter we outline the basis of the growing worldwide interest in hydrogen energy and examine some of the important issues relating to the future development of hydrogen as an energy vector. As a ‘snapshot’ of international activity, we note, for example, that Japan regards the development and dissemination of fuel cells and hydrogen technologies as essential: the Ministry of Economy and Industry (METI) has set numerical targets of 5 million fuel cell vehicles and10 million kW for the total power generation by stationary fuel cells by 2020. To meet these targets, METI has allocated an annual budget of some £150 million over four years.

scholarly journals [NiFe], [FeFe], and [Fe] hydrogenase models from isomers

2020 ◽  
Vol 6 (24) ◽  
pp. eaaz8181
Author(s):  
Seiji Ogo ◽  
Takahiro Kishima ◽  
Takeshi Yatabe ◽  
Keishi Miyazawa ◽  
Ryunosuke Yamasaki ◽  
...  
Keyword(s):  
Nuclear Magnetic Resonance ◽  
Magnetic Resonance ◽  
Catalytic Properties ◽  
Electrochemical Measurement ◽  
Hydrogen Energy ◽  
X Ray ◽  
Energy Economy ◽  
Hydrogenase Enzymes ◽  
Nuclear Magnetic

The study of hydrogenase enzymes (H2ases) is necessary because of their importance to a future hydrogen energy economy. These enzymes come in three distinct classes: [NiFe] H2ases, which have a propensity toward H2 oxidation; [FeFe] H2ases, which have a propensity toward H2 evolution; and [Fe] H2ases, which catalyze H− transfer. Modeling these enzymes has so far treated them as different species, which is understandable given the different cores and ligand sets of the natural molecules. Here, we demonstrate, using x-ray analysis and nuclear magnetic resonance, infrared, Mössbauer spectroscopies, and electrochemical measurement, that the catalytic properties of all three enzymes can be mimicked with only three isomers of the same NiFe complex.

scholarly journals Properties and Applications of Metal (M) dodecahydro-closo-dodecaborates (Mn=1,2B12H12) and Their Implications for Reversible Hydrogen Storage in the Borohydrides

Inorganics ◽  
2018 ◽  
Vol 6 (4) ◽  
pp. 106 ◽  
Author(s):  
Aiden Grahame ◽  
Kondo-François Aguey-Zinsou
Keyword(s):  
Solid State ◽  
Hydrogen Storage ◽  
Sustainable Energy ◽  
Energy Carrier ◽  
Hydrogen Energy ◽  
Storage Method ◽  
Modern Chemistry ◽  
Energy Economy ◽  
Hydrogen Technologies

Hydrogen has long been proposed as a versatile energy carrier that could facilitate a sustainable energy future. For an energy economy centred around hydrogen to function, a storage method is required that is optimised for both portable and stationary applications and is compatible with existing hydrogen technologies. Storage by chemisorption in borohydride species emerges as a promising option because of the advantages of solid-state storage and the unmatched hydrogen energy densities that borohydrides attain. One of the most nuanced challenges limiting the feasibility of borohydride hydrogen storage is the irreversibility of their hydrogen storage reactions. This irreversibility has been partially attributed to the formation of stable dodecahydro-closo-dodecaborates (Mn=1,2B12H12) during the desorption of hydrogen. These dodecaborates have an interesting set of properties that are problematic in the context of borohydride decomposition but suggest a variety of useful applications when considered independently. In this review, dodecaborates are explored within the borohydride thermolysis system and beyond to present a holistic discussion of the most important roles of the dodecaborates in modern chemistry.

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