Intramolecular Activation of Pepsinogen

1977 ◽  
pp. 85-102 ◽  
Author(s):  
Jean A. Hartsuck ◽  
Joseph Marciniszyn ◽  
Jung San Huang ◽  
Jordan Tang
Keyword(s):  
Intramolecular Activation

Cyclometallation Reactions in the Fe(dprpe)2 System [dprpe = 1,2-Bis(dipropylphosphino)ethane].

1999 ◽  
Vol 52 (11) ◽  
pp. 1005 ◽  
Author(s):  
Murray V. Baker ◽  
Leslie D. Field
Keyword(s):  
Methyl Group ◽  
Thermal Elimination ◽  
Intramolecular Activation

Thermal elimination of methane from cis-FeH(CH3)(dprpe)2 [dprpe = 1,2-bis(dipropylphosphino)ethane] or photochemical elimination of dihydrogen from FeH2(dprpe)2 leads to the formation of three cyclometallation products. The products are believed to arise via a pathway in which the coordinatively unsaturated intermediate Fe(dprpe)2 undergoes intramolecular activation of a C–H bond of a dprpe methyl group. 1H and 31P n.m.r. spectroscopy were used to characterize the products and explore the reactions leading to their formation.

scholarly journals C(sp2)–Si Bond Functionalization through Intramolecular Activation by Alkoxides

2020 ◽  
Author(s):  
Sebastien Curpanen ◽  
Giovanni Poli ◽  
Julie Oble ◽  
Alejandro Perez-Luna
Keyword(s):  
Bond Functionalization ◽  
Intramolecular Activation

Formation of a chelating .sigma.-allyl by the intramolecular activation of a cyclopropylphosphine. Synthesis and crystal structure of [PdCl(P(tert-Bu)2CH:C(CH3)CH2)]2

1983 ◽  
Vol 2 (7) ◽  
pp. 917-921 ◽  
Author(s):  
Wiley J. Youngs ◽  
James Mahood ◽  
Barbara L. Simms ◽  
Paul N. Swepston ◽  
James A. Ibers ◽  
...  
Keyword(s):  
Crystal Structure ◽  
Synthesis And Crystal Structure ◽  
Intramolecular Activation

Intramolecular-activation evidence for the unexpected Beckmann fragmentation of C(1)-substituted-7-bromonorbornane-2-ones

Tetrahedron ◽  
2004 ◽  
Vol 60 (42) ◽  
pp. 9447-9451 ◽  
Author(s):  
Antonio García Martínez ◽  
Enrique Teso Vilar ◽  
Amelia García Fraile ◽  
Santiago de la Moya Cerero ◽  
Beatriz Lora Maroto
Keyword(s):  
Intramolecular Activation
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