Solvent Effects on Molecular Electric Properties

2017 ◽  
pp. 741-794 ◽  
Author(s):  
Miroslav Medved’ ◽  
Šimon Budzák ◽  
Wojciech Bartkowiak ◽  
Heribert Reis
Keyword(s):  
Solvent Effects ◽  
Electric Properties

MP2, DFT-D, and PCM study of the HMB–TCNE complex: Thermodynamics, electric properties, and solvent effects

2008 ◽  
Vol 108 (9) ◽  
pp. 1533-1545 ◽  
Author(s):  
Ondrej Kysel ◽  
Šimon Budzák ◽  
Miroslav Medveď ◽  
Pavel Mach
Keyword(s):  
Solvent Effects ◽  
Electric Properties

Solvent Effects on Molecular Electric Properties

2015 ◽  
pp. 1-54
Author(s):  
Miroslav Medved’ ◽  
Šimon Budzák ◽  
Wojciech Bartkowiak ◽  
Heribert Reis
Keyword(s):  
Solvent Effects ◽  
Electric Properties

Electric Properties of Liquid Metals and Semiconductors

1972 ◽  
Vol 106 (3) ◽  
pp. 393 ◽  
Author(s):  
V.A. Alekseev ◽  
Aleksandr A. Andreev ◽  
V.Ya. Prokhorenko
Keyword(s):  
Liquid Metals ◽  
Electric Properties

A system of experimental studies of electric properties of rocks in the inert medium

2018 ◽  
Vol 40 (1) ◽  
pp. 93-106
Author(s):  
M. V. Kravchuk ◽  
V. A. Korchyn ◽  
V. P. Kobolev ◽  
N. I. Novik
Keyword(s):  
Experimental Studies ◽  
Electric Properties ◽  
Inert Medium

Surface confinement induces the formation of solid-like insulating ionic liquid nanostructures

2017 ◽  
Author(s):  
Massimiliano Galluzzi ◽  
Simone Bovio ◽  
Paolo Milani ◽  
Alessandro Podestà
Keyword(s):  
Ionic Liquid ◽  
Electrical Properties ◽  
Electric Fields ◽  
Relative Dielectric Constant ◽  
Ionic Mobility ◽  
Electric Properties ◽  
Bulk Liquid ◽  
Structural Reorganization ◽  
Surface Confinement ◽  
Insulator Layers

We report on the modification of the electric properties of the imidazolium-based [BMIM][NTf2] ionic liquid upon surface confinement in the sub-monolayer regime. Solid-like insulating nanostructures of [BMIM][NTf2] spontaneously form on a variety of insulating substrates, at odd with the liquid and conductive nature of the same substances in the bulk phase. A systematic spatially resolved investigation by atomic force microscopy of the morphological, mechanical and electrical properties of [BMIM][NTf2] nanostructures showed that this liquid substance rearranges into lamellar nanostructures with a high degree of vertical order and enhanced resistance to mechanical compressive stresses and very intense electric fields, denoting a solid-like character. The morphological and structural reorganization has a profound impact on the electric properties of supported [BMIM][NTf2] islands, which behave like insulator layers with a relative dielectric constant between 3 and 5, comparable to those of conventional ionic solids, and significantly smaller than those measured in the bulk ionic liquid. These results suggest that in the solid-like ordered domains confined either at surfaces or inside the pores of the nanoporous electrodes of photo-electrochemical devices, the ionic mobility and the overall electrical properties can be significantly perturbed with respect to the bulk liquid phase, which would likely influence the<br>performance of the devices.<br>

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