This article investigates the potential of the point contact Andreev reflection spectroscopy (PCARS) technique for measuring the symmetry of the energy gap and other key parameters of various 0-, 1-, and 2-dimensional superconducting systems. It begins with a brief description of PCARS, explaining what a point contact is and how it can be made and the conditions under which a PC is ballistic, as well as why and to what extent a PC between normal metals is spectroscopic. It then discusses the basics of Andreev reflection and the length scales in mesoscopic systems before considering the limits of applicability of PCARS for spectroscopy of ‘small’ superconductors. Finally, it reviews some examples of PCARS in quasi-0D, quasi-1D and quasi-2D superconductors.