Electrolytic Degradation Within Cathode Materials

2016 ◽  
pp. 1011-1016
Author(s):  
Parin Rafiei ◽  
Frank Hiltmann ◽  
Margaret Hyland ◽  
Bryony James ◽  
Barry Welch
Keyword(s):  
Cathode Materials

NEW CATHODE MATERIALS FOR INERT AND OXIDIZING ATMOSPHERE PLASMA APPLICATION

1990 ◽  
Vol 51 (C5) ◽  
pp. C5-403-C5-410
Author(s):  
A. A. SADEK ◽  
K. KUSUMOTO ◽  
M. USHIO ◽  
F. MATSUDA
Keyword(s):  
Cathode Materials ◽  
Oxidizing Atmosphere

Rational Design of Quasi Zero-Strain NCM Cathode Materials for Minimizing Volume Change Effects in All-Solid-State Batteries

2019 ◽  
Author(s):  
Florian Strauss ◽  
Lea de Biasi ◽  
A-Young Kim ◽  
Jonas Hertle ◽  
Simon Schweidler ◽  
...  
Keyword(s):  
Solid State ◽  
Solid Electrolyte ◽  
Cathode Materials ◽  
Rational Design ◽  
Electrode Materials ◽  
Cycling Performance ◽  
Mechanical Degradation ◽  
Volume Changes ◽  
Solid State Batteries ◽  
All Solid State Batteries

Measures to improve the cycling performance and stability of bulk-type all-solid-state batteries (SSBs) are currently being developed with the goal of substituting conventional Li-ion battery (LIB) technology. As known from liquid electrolyte based LIBs, layered oxide cathode materials undergo volume changes upon (de)lithiation, causing mechanical degradation due to particle fracture, among others. Unlike solid electrolytes, liquid electrolytes are somewhat capable of accommodating morphological changes. In SSBs, the rigidity of the materials used typically leads to adverse contact loss at the interfaces of cathode material and solid electrolyte during cycling. Hence, designing zero- or low-strain electrode materials for application in next-generation SSBs is desirable. In the present work, we report on novel Co-rich NCMs, NCM361 (60% Co) and NCM271 (70% Co), showing minor volume changes up to 4.5 V vs Li<sup>+</sup>/Li, as determined by <i>operando</i> X-ray diffraction and pressure measurements of LIB pouch and pelletized SSB cells, respectively. Both cathode materials exhibit good cycling performance when incorporated into SSB cells using argyrodite Li<sub>6</sub>PS<sub>5</sub>Cl solid electrolyte, albeit their morphology and secondary particle size have not yet been optimized.

Rational Design of Quasi Zero-Strain NCM Cathode Materials for Minimizing Volume Change Effects in All-Solid-State Batteries

2019 ◽  
Author(s):  
Florian Strauss ◽  
Lea de Biasi ◽  
A-Young Kim ◽  
Jonas Hertle ◽  
Simon Schweidler ◽  
...  
Keyword(s):  
Solid State ◽  
Solid Electrolyte ◽  
Cathode Materials ◽  
Rational Design ◽  
Electrode Materials ◽  
Cycling Performance ◽  
Mechanical Degradation ◽  
Volume Changes ◽  
Solid State Batteries ◽  
All Solid State Batteries

Measures to improve the cycling performance and stability of bulk-type all-solid-state batteries (SSBs) are currently being developed with the goal of substituting conventional Li-ion battery (LIB) technology. As known from liquid electrolyte based LIBs, layered oxide cathode materials undergo volume changes upon (de)lithiation, causing mechanical degradation due to particle fracture, among others. Unlike solid electrolytes, liquid electrolytes are somewhat capable of accommodating morphological changes. In SSBs, the rigidity of the materials used typically leads to adverse contact loss at the interfaces of cathode material and solid electrolyte during cycling. Hence, designing zero- or low-strain electrode materials for application in next-generation SSBs is desirable. In the present work, we report on novel Co-rich NCMs, NCM361 (60% Co) and NCM271 (70% Co), showing minor volume changes up to 4.5 V vs Li<sup>+</sup>/Li, as determined by <i>operando</i> X-ray diffraction and pressure measurements of LIB pouch and pelletized SSB cells, respectively. Both cathode materials exhibit good cycling performance when incorporated into SSB cells using argyrodite Li<sub>6</sub>PS<sub>5</sub>Cl solid electrolyte, albeit their morphology and secondary particle size have not yet been optimized.

Stabilization of Nickel-Rich Layered Cathode Materials of High Energy Density by Ca Doping

2018 ◽  
Vol 28 (5) ◽  
pp. 273-278
Author(s):  
Beomhee Kang ◽  
Soonhyun Hong ◽  
Hongkwan Yoon ◽  
Dojin Kim ◽  
Chunjoong Kim
Keyword(s):  
Energy Density ◽  
Cathode Materials ◽  
High Energy ◽  
High Energy Density ◽  
Ca Doping ◽  
Layered Cathode Materials

Changes in the Shape and Properties of the Precursor of the Rich-Ni Cathode Materials by Ammonia Concentration

2020 ◽  
Vol 30 (11) ◽  
pp. 636-640
Author(s):  
Seonhye Park ◽  
Soonhyun Hong ◽  
Hyeonggwon Jeon ◽  
Chunjoong Kim
Keyword(s):  
Cathode Materials ◽  
Ammonia Concentration ◽  
The Rich

ChemInform Abstract: MOLTEN CARBONATE FUEL CELL CATHODE MATERIALS STUDY

1985 ◽  
Vol 16 (7) ◽  
Author(s):  
C. E. BAUMGARTNER ◽  
R. H. ARENDT ◽  
C. D. IACOVANGELO ◽  
B. R. KARAS
Keyword(s):  
Fuel Cell ◽  
Cathode Materials ◽  
Molten Carbonate Fuel Cell ◽  
Molten Carbonate ◽  
Fuel Cell Cathode ◽  
Carbonate Fuel Cell ◽  
Cell Cathode

Stabilizing transition metal vacancy induced oxygen redox by Co2+/Co3+ redox and sodium‐site doping for layered cathode materials

2021 ◽  
Author(s):  
Xun-Lu Li ◽  
Jian Bao ◽  
Zulipiya Shadike ◽  
Qin-Chao Wang ◽  
Xiao-Qing Yang ◽  
...  
Keyword(s):  
Transition Metal ◽  
Cathode Materials ◽  
Layered Cathode Materials ◽  
Metal Vacancy

Understanding the Feasibility of Manganese Substitution for Cobalt in the Synthesis of Nickel-Rich and Cobalt-Free Cathode Materials

2021 ◽  
Author(s):  
Kaibin Fang ◽  
Qian Xie ◽  
Chengyun Wang ◽  
Xiulian Qiu ◽  
Yali Wang ◽  
...  
Keyword(s):  
Cathode Materials
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