Using the factorization approach and considering the contributions of the current–current, QCD penguin and electroweak penguin operators at the leading approximation, the decay amplitudes and decay widths of [Formula: see text] and [Formula: see text] transitions, where q = u, d, s and P and V are pseudoscalar and vector mesons, are calculated in terms of the transition form factors of the Bq→Dq and [Formula: see text]. Having computed those form factors in three-point QCD sum rules, the branching fraction for these decays are also evaluated. A comparison of our results with the predictions of the perturbative QCD as well as the existing experimental data is presented.