Interpretation of Kinetic Isotope Effects in Enzymatic Cleavage of Carbon-Hydrogen Bonds

Challenges and Advances in Computational Chemistry and Physics - Kinetics and Dynamics ◽

10.1007/978-90-481-3034-4_17 ◽

2010 ◽

pp. 465-479

Author(s):

Willem Siebrand ◽

Zorka Smedarchina

Keyword(s):

Hydrogen Bonds ◽

Isotope Effects ◽

Kinetic Isotope Effects ◽

Enzymatic Cleavage ◽

Kinetic Isotope ◽

Carbon Hydrogen Bonds

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Energetics, proton transfer rates, and kinetic isotope effects in bent hydrogen bonds

Journal of the American Chemical Society ◽

10.1021/ja00040a055 ◽

1992 ◽

Vol 114 (14) ◽

pp. 5849-5856 ◽

Cited By ~ 24

Author(s):

Xiaofeng Duan ◽

Steve Scheiner

Keyword(s):

Hydrogen Bonds ◽

Proton Transfer ◽

Isotope Effects ◽

Kinetic Isotope Effects ◽

Transfer Rates ◽

Kinetic Isotope

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Geometrical and Kinetic Isotope Effects on R–H(D)···R Type Intramolecular Hydrogen Bonds (R = CH2, NH, and O) Using a Multi-Component Molecular Orbital Method

Bulletin of the Chemical Society of Japan ◽

10.1246/bcsj.81.820 ◽

2008 ◽

Vol 81 (7) ◽

pp. 820-825 ◽

Cited By ~ 11

Author(s):

Yoko Kikuta ◽

Takayoshi Ishimoto ◽

Umpei Nagashima

Keyword(s):

Hydrogen Bonds ◽

Molecular Orbital ◽

Isotope Effects ◽

Kinetic Isotope Effects ◽

Orbital Method ◽

Molecular Orbital Method ◽

Intramolecular Hydrogen Bonds ◽

Kinetic Isotope ◽

Intramolecular Hydrogen

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Kinetic isotope effects for silylene insertions into oxygen-hydrogen and silicon-hydrogen bonds

Inorganic Chemistry ◽

10.1021/ic50218a068 ◽

1981 ◽

Vol 20 (4) ◽

pp. 1302-1304 ◽

Cited By ~ 17

Author(s):

Kent P. Steele ◽

William P. Weber

Keyword(s):

Hydrogen Bonds ◽

Isotope Effects ◽

Kinetic Isotope Effects ◽

Kinetic Isotope

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ChemInform Abstract: KINETIC ISOTOPE EFFECTS FOR SILYLENE INSERTIONS INTO OXYGEN-HYDROGEN AND SILICON-HYDROGEN BONDS

Chemischer Informationsdienst ◽

10.1002/chin.198129289 ◽

1981 ◽

Vol 12 (29) ◽

Author(s):

K. P. STEELE ◽

W. P. WEBER

Keyword(s):

Hydrogen Bonds ◽

Isotope Effects ◽

Kinetic Isotope Effects ◽

Kinetic Isotope

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ChemInform Abstract: Energetics, Proton Transfer Rates, and Kinetic Isotope Effects in Bent Hydrogen Bonds

ChemInform ◽

10.1002/chin.199243055 ◽

2010 ◽

Vol 23 (43) ◽

pp. no-no

Author(s):

X. DUAN ◽

S. SCHEINER

Keyword(s):

Hydrogen Bonds ◽

Proton Transfer ◽

Isotope Effects ◽

Kinetic Isotope Effects ◽

Transfer Rates ◽

Kinetic Isotope

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Sizeable Increase of Kinetic Isotope Effects and Tunnelling in Coupled Electron–Proton Transfers in Presence of the Quaternary Ions. PCET Processes and Hydrogen Tunnelling as a “Probe” for Structuring and Dynamical Phenomena in Water Solution

Zeitschrift für Physikalische Chemie ◽

10.1524/zpch.2012.0150 ◽

2011 ◽

pp. 110923034559006

Author(s):

Cvijeta Jakobušić Brala ◽

Ana Karković ◽

Ivana Sajenko ◽

Viktor Pilepić ◽

Stanko Uršić

Keyword(s):

Water Solution ◽

Isotope Effects ◽

Kinetic Isotope Effects ◽

Kinetic Isotope ◽

Proton Transfers ◽

Sizeable Increase

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Primary and secondary kinetic isotope effects in proton (H+/D+) and chloronium ion (35Cl+/37Cl+) affinities

Journal of Mass Spectrometry ◽

10.1002/jms.219 ◽

2001 ◽

Vol 36 (10) ◽

pp. 1140-1148 ◽

Cited By ~ 20

Author(s):

F�bio Cesar Gozzo ◽

Marcos N. Eberlin

Keyword(s):

Isotope Effects ◽

Kinetic Isotope Effects ◽

Kinetic Isotope

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Theoretical Simulations of Heavy-Atom Kinetic Isotope Effects in Aliphatic Claisen Rearrangement

The Journal of Physical Chemistry A ◽

10.1021/acs.jpca.0c07784 ◽

2020 ◽

Vol 124 (51) ◽

pp. 10678-10686

Author(s):

Yuqing Xu ◽

Kin-Yiu Wong ◽

Meishan Wang ◽

Desheng Liu ◽

Wenkai Zhao ◽

...

Keyword(s):

Claisen Rearrangement ◽

Isotope Effects ◽

Heavy Atom ◽

Kinetic Isotope Effects ◽

Kinetic Isotope ◽

Theoretical Simulations

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Stereochemistry and kinetic isotope effects in the decarboxylation of S-adenosylmethionine catalyzed by the pyruvyl enzyme, S-adenosylmethionine decarboxylase.

Journal of Biological Chemistry ◽

10.1016/s0021-9258(19)69595-5 ◽

1981 ◽

Vol 256 (7) ◽

pp. 3233-3239

Author(s):

R.R. Allen ◽

J.P. Klinman

Keyword(s):

Isotope Effects ◽

Kinetic Isotope Effects ◽

Adenosylmethionine Decarboxylase ◽

Kinetic Isotope

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Ab Initio Density Functional Calculations of Deuterium Kinetic Isotope Effects for Decomposition of Dimethylnitramine

The Journal of Physical Chemistry A ◽

10.1021/jp962326t ◽

1997 ◽

Vol 101 (7) ◽

pp. 1370-1373 ◽

Cited By ~ 11

Author(s):

Nathan J. Harris ◽

Koop Lammertsma

Keyword(s):

Ab Initio ◽

Density Functional Calculations ◽

Density Functional ◽

Isotope Effects ◽

Kinetic Isotope Effects ◽

Kinetic Isotope

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