Synthesis of tetranuclear butterfly clusters RuM3(?-H)(CO)12(?4-?1-?1-?1-?2-C2Fc) (M=Ru, Os; Fc=ferrocenyl) and RuOs3(CO)12(?4-?1-?1-?2-?2-HC2Me) from trinuclear acetylide precursors. Fluctuation of ?4-bonded acetylide ligand

1995 ◽  
Vol 44 (11) ◽  
pp. 2198-2199 ◽  
Author(s):  
A. A. Koridze ◽  
V. I. Zdanovich ◽  
V. Yu. Lagunova ◽  
A. M. Sheloumov ◽  
F. M. Dolgushin ◽  
...  
Keyword(s):  
Acetylide Ligand

Effects of extending the π-conjugation of the acetylide ligand on the photophysics and reverse saturable absorption of Pt(ii) bipyridine bisacetylide complexes

2016 ◽  
Vol 18 (41) ◽  
pp. 28674-28687 ◽  
Author(s):  
Taotao Lu ◽  
Chengzhe Wang ◽  
Levi Lystrom ◽  
Chengkui Pei ◽  
Svetlana Kilina ◽  
...  
Keyword(s):  
Excited State ◽  
Excited States ◽  
Substituent Effect ◽  
Excited State Absorption ◽  
Saturable Absorption ◽  
Reverse Saturable Absorption ◽  
Triplet Excited State ◽  
Near Ir ◽  
Terminal Substituent ◽  
Acetylide Ligand

Extending the acetylide ligand π-conjugation diminishes the terminal substituent effect on the lowest excited states, but expands the triplet excited-state absorption to the near-IR region.

Synthesis of the Tetranuclear Clusters RuM3H(C⋮CFc)(CO)12(M = Ru, Os; Fc = Ferrocenyl), Containing a Fluxional μ4-Acetylide Ligand. Structure of a Mixed Crystal Containing Tetranuclear (Ru4H(C⋮CFc)(CO)12) and Trinuclear (Ru3H(C⋮CFc)(CO)9) Ruthenium Complexes

1997 ◽  
Vol 16 (11) ◽  
pp. 2285-2290 ◽  
Author(s):  
Avthandil A. Koridze ◽  
Valeria I. Zdanovich ◽  
Aleksey M. Sheloumov ◽  
Veronika Yu. Lagunova ◽  
Pavel V. Petrovskii ◽  
...  
Keyword(s):  
Mixed Crystal ◽  
Ruthenium Complexes ◽  
Ligand Structure ◽  
Tetranuclear Clusters ◽  
Acetylide Ligand

Metal Cation Induced Modulation of the Photophysical Properties of a Platinum(II) Complex Featuring a Dipicolylanilino-Acetylide Ligand

2011 ◽  
Vol 2011 (8) ◽  
pp. 1255-1259 ◽  
Author(s):  
Pierre-Henri Lanoë ◽  
Jean-Luc Fillaut ◽  
Véronique Guerchais ◽  
Hubert Le Bozec ◽  
J. A. Gareth Williams
Keyword(s):  
Metal Cation ◽  
Photophysical Properties ◽  
Acetylide Ligand

scholarly journals Rotation of the acetylide ligand on the triangular face of tungsten-diruthenium clusters. Crystal structure and solution dynamics of LWM2(CO)8(CCPh), L = C5H5, C5Me5 and M = Os, Ru

Polyhedron ◽  
1989 ◽  
Vol 8 (15) ◽  
pp. 2003-2006 ◽  
Author(s):  
Yun Chi ◽  
Bang-Ji Liu ◽  
Gen-Hsiang Lee ◽  
Shie-Ming Peng
Keyword(s):  
Crystal Structure ◽  
Triangular Face ◽  
Solution Dynamics ◽  
Acetylide Ligand

Tuning the Excited-state Properties of Cyclometalated Platinum (II) Complexes of 6-Phenyl-2,2′-bipyridine by Ancillary Acetylide Ligand

2010 ◽  
Vol 21 (2) ◽  
pp. 196-199 ◽  
Author(s):  
Wu Zi-Xin ◽  
Wu Li-Zhu ◽  
Yang Qing-Zheng ◽  
Zhang Li-Ping ◽  
Tung Chen-Ho
Keyword(s):  
Excited State ◽  
Acetylide Ligand

Synthesis and Photophysics of Platinum(II) 6-Phenyl-4-(9,9-dihexylfluoren-2-yl)-2,2′-bipyridine Complexes with Phenothiazinyl Acetylide Ligand

2010 ◽  
Vol 114 (26) ◽  
pp. 7055-7062 ◽  
Author(s):  
Jing Yi ◽  
Bingguang Zhang ◽  
Pin Shao ◽  
Yunjing Li ◽  
Wenfang Sun
Keyword(s):  
Acetylide Ligand

ChemInform Abstract: A New Diruthenium(II,III) Compound, Ru2(CCPh)(PhNpy)4·2 CH2Cl2, with an Axial η1-Acetylide Ligand.

1986 ◽  
Vol 17 (26) ◽  
Author(s):  
A. R. CHAKRAVARTY ◽  
F. A. COTTON
Keyword(s):  
Acetylide Ligand

scholarly journals Syntheses and Reactivity Studies of the Carbido-Alkylidyne Cluster Complexes LWRu4(μ5-C)(μ-CPh)(CO)12and LWRu5(μ6-C)(μ-CPh)(CO)14, L = Cp and Cp*, Obtained from Reversible Scission of Acetylide Ligand

2001 ◽  
Vol 20 (1) ◽  
pp. 215-223 ◽  
Author(s):  
Shu-Fen Hwang ◽  
Yun Chi ◽  
Shun-Jean Chiang ◽  
Shie-Ming Peng ◽  
Gene-Hsiang Lee
Keyword(s):  
Cluster Complexes ◽  
Acetylide Ligand

Oxidative decarbonation of an acetylide ligand

1986 ◽  
Vol 5 (11) ◽  
pp. 2388-2389 ◽  
Author(s):  
Wolfgang. Bernhardt ◽  
Heinrich. Vahrenkamp
Keyword(s):  
Acetylide Ligand

A new diruthenium(II,III) compound, Ru2(CCPh)(PhNpy)4·2CH2Cl2, with an axial η1-acetylide ligand

1986 ◽  
Vol 113 (1) ◽  
pp. 19-26 ◽  
Author(s):  
Akhil R. Chakravarty ◽  
F.Albert Cotton
Keyword(s):  
Acetylide Ligand
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