Connection of the solubility and integral heats of hydration with the structure of aqueous solutions of electrolytes formed from ions with negative hydration

1974 ◽  
Vol 14 (6) ◽  
pp. 1034-1036
Author(s):  
A. S. Solovkin
Keyword(s):  
Aqueous Solutions ◽  
Negative Hydration ◽  
Solutions Of Electrolytes ◽  
Structure Of Aqueous Solutions

Structure of aqueous solutions. Librational band studies of hydrophobic and hydrophilic effects in solutions of electrolytes and nonelectrolytes

1976 ◽  
Vol 80 (12) ◽  
pp. 1346-1350 ◽  
Author(s):  
David W. James ◽  
Richard F. Armishaw ◽  
Ray L. Frost
Keyword(s):  
Aqueous Solutions ◽  
Solutions Of Electrolytes ◽  
Structure Of Aqueous Solutions

Kinematic Shear Viscosity of Water, Aqueous Solutions of Electrolytes, and Ethanol

2015 ◽  
Vol 60 (9) ◽  
pp. 854-860 ◽  
Author(s):  
V.M. Makhlaichuk ◽  
Keyword(s):  
Aqueous Solutions ◽  
Shear Viscosity ◽  
Solutions Of Electrolytes

Gas holdup in bubbled beds of aqueous solutions of electrolytes

1977 ◽  
Vol 42 (9) ◽  
pp. 2642-2650
Author(s):  
F. Kaštánek ◽  
J. Kratochvíl ◽  
J. Pata ◽  
M. Rylek
Keyword(s):  
Aqueous Solutions ◽  
Gas Holdup ◽  
Solutions Of Electrolytes

The metachor as a characteristic of the association of electrolytes in aqueous solutions

1984 ◽  
Vol 49 (5) ◽  
pp. 1061-1078 ◽  
Author(s):  
Jiří Čeleda ◽  
Stanislav Škramovský
Keyword(s):  
Aqueous Solutions ◽  
Apparent Volume ◽  
Solutions Of Electrolytes ◽  
Molal Volumes ◽  
The Difference ◽  
High Concentrations ◽  
Experimental Values ◽  
Suitable Characteristic ◽  
Association Of Ions ◽  
Very High

Based on the earlier paper introducing a concept of the apparent parachor of a solute in the solution, we have eliminated in the present work algebraically the effect which is introduced into this quantity by the additivity of the apparent molal volumes. The difference remaining from the apparent parachor after substracting the contribution corresponding to the apparent volume ( for which the present authors suggest the name metachor) was evaluated from the experimental values of the surface tension of aqueous solutions for a set of 1,1-, 1,2- and 2,1-valent electrolytes. This difference showed to be independent of concentration up to the very high values of the order of units mol dm-3 but it was directly proportional to the number of the free charges (with a proportionality factor 5 ± 1 cm3 mol-1 identical for all studied electrolytes). The metachor can be, for this reason, a suitable characteristic for detection of the association of ions and formation of complexes in the solutions of electrolytes, up to high concentrations where other methods are failing.

The salting-out effect and phase separation in aqueous solutions of electrolytes and poly(ethylene glycol)

Polymer ◽  
2005 ◽  
Vol 46 (8) ◽  
pp. 2567-2572 ◽  
Author(s):  
Michael J. Hey ◽  
Daniel P. Jackson ◽  
Hong Yan
Keyword(s):  
Phase Separation ◽  
Ethylene Glycol ◽  
Aqueous Solutions ◽  
Poly Ethylene Glycol ◽  
Salting Out ◽  
Solutions Of Electrolytes ◽  
Poly Ethylene
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