A new method of synthesizing macrocyclic compounds

1968 ◽  
Vol 17 (4) ◽  
pp. 735-740 ◽  
Author(s):  
S. Z. Taits ◽  
�. A. Krasnyanskaya ◽  
Ya. L. Gol'dfarb
Keyword(s):  
New Method ◽  
Macrocyclic Compounds

New method for the synthesis of macrocyclic compounds

1972 ◽  
Vol 8 (2) ◽  
pp. 149-155 ◽  
Author(s):  
S. Z. Taits ◽  
O. A. Kalinovskii ◽  
V. S. Bogdanov ◽  
Ya. L. Gol'dfarb
Keyword(s):  
New Method ◽  
Macrocyclic Compounds

New method of synthesis of macrocyclic compounds

1970 ◽  
Vol 19 (10) ◽  
pp. 2189-2194 ◽  
Author(s):  
O. A. Kalinovskii ◽  
S. Z. Taits ◽  
Ya. L. Gol'dfarb
Keyword(s):  
New Method ◽  
Macrocyclic Compounds

A new method of syntheses of 18-membered macrocyclic diphenyltin(IV) compounds and crystal structures of {Ph2Sn[S(C6H3NO)O]}3·Y (Y = 2H2O or 4C6H6) and {Ph3Sn[S(C6H3NO)O]SnPh3(EtOH)}·[EtOH]

2004 ◽  
Vol 82 (5) ◽  
pp. 608-615 ◽  
Author(s):  
Chunlin Ma ◽  
Qin Jiang ◽  
Rufen Zhang
Keyword(s):  
Crystal Structure ◽  
Crystal Structures ◽  
New Method ◽  
Macrocyclic Compounds ◽  
X Ray ◽  
Stacking Interaction ◽  
Π Stacking ◽  
Triphenyltin Chloride ◽  
Π Stacking Interaction ◽  
Solvent Molecules

Two diphenyltin(IV) compounds: {Ph2Sn[S(C6H3NO)O]}3·Y (Y = 2H2O, 1; 4C6H6, 2) have been unexpectedly obtained by the reactions of triphenyltin chloride with 2-mercaptonicotinic acid in the presence of Et3N. However, by the reaction of the same reactants in the presence of EtONa, only a new triphenyltin(IV) compound ({Ph3Sn[S(C6H3NO)O]SnPh3(EtOH)}·[EtOH], 3) was obtained. The X-ray analyses reveal that compounds 1 and 2 are trinuclear, 18-membered macrocyclic compounds while 3 is a dinuclear compound. Specially, π-π stacking interaction was recognized in crystals of compound 1, which makes it a dimer. Co-crystallization was found in the crystals of all the three compounds 1, 2, and 3, the co-crystallized solvent molecules are water, benzene, and ethanol molecules, respectively. A possible dephenylation mechanism of 1 and 2 was illustrated in detail.Key words: triphenyltin, 2-mercaptonicotinic acid, dephenylation, macrocyclic, π-π stacking interaction, co-crystallization, crystal structure.

New method for the synthesis of macrocyclic compounds

1968 ◽  
Vol 17 (3) ◽  
pp. 555-558
Author(s):  
S. Z. Taits ◽  
F. D. Alashev ◽  
Ya. L. Gol'dfarb
Keyword(s):  
New Method ◽  
Macrocyclic Compounds

New method for the synthesis of macrocyclic compounds

1973 ◽  
Vol 9 (1) ◽  
pp. 13-17 ◽  
Author(s):  
S. Z. Taits ◽  
V. N. Bulgakova ◽  
Ya. L. Gol'dfarb
Keyword(s):  
New Method ◽  
Macrocyclic Compounds

New method for the synthesis of macrocyclic compounds

1973 ◽  
Vol 9 (5) ◽  
pp. 576-582 ◽  
Author(s):  
S. Z. Taits ◽  
O. A. Kalinovskii ◽  
B. V. Lopatin ◽  
Ya. L. Gol'dfarb
Keyword(s):  
New Method ◽  
Macrocyclic Compounds
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