Statistical thermodynamics of adsorption from multicomponent liquid mixtures on heterogeneous solid surfaces

1981 ◽  
Vol 112 (1) ◽  
pp. 59-71 ◽  
Author(s):  
Małgorzata Borówko ◽  
Mieczysław Jaroniec ◽  
Władysław Rudziński
Keyword(s):  
Statistical Thermodynamics ◽  
Liquid Mixtures ◽  
Solid Surfaces ◽  
Thermodynamics Of Adsorption ◽  
Multicomponent Liquid Mixtures ◽  
Heterogeneous Solid

Competitive adsorption from multicomponent non-electrolytic liquid mixtures on heterogeneous solid surfaces

1993 ◽  
Vol 124 (3) ◽  
pp. 229-242 ◽  
Author(s):  
Anna Derylo-Marczewska ◽  
M. Jaroniec ◽  
J. Oscik ◽  
A. W. Marczewski
Keyword(s):  
Competitive Adsorption ◽  
Liquid Mixtures ◽  
Solid Surfaces ◽  
Heterogeneous Solid

scholarly journals Effects of Surface Heterogeneity in Adsorption from Binary Solutions on Modified Silica Gels

1987 ◽  
Vol 4 (4) ◽  
pp. 224-229
Author(s):  
J. Goworek
Keyword(s):  
Surface Heterogeneity ◽  
Liquid Mixtures ◽  
Distribution Functions ◽  
Solid Surfaces ◽  
Silica Gels ◽  
Modified Silica ◽  
Binary Solutions ◽  
Isotherm Equation ◽  
Heterogeneous Solid ◽  
Modified Silica Gels

The adsorption of benzene from cyclohexane solutions on modified silica gels is analysed using expressions derived from the model of adsorption of binary solutions on heterogeneous solid surfaces. The adsorption equation is found to represent the data for several systems and leads to a method for estimating the energetical heterogeneity of the adsorbent surface. The energy distribution functions for investigated systems are calculated. The same adsorption data are analysed using the simple form of isotherm equation for adsorption of binary liquid mixtures on heterogeneous solid surfaces. The results obtained by using two different methods for the same adsorption systems are discussed.

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