Analysis of the Rydberg structure in the vapor-phase electronic absorption spectrum of (η7-cycloheptatrienyl)(η5-cyclopentadienyl) chromium

1999 ◽  
Vol 48 (9) ◽  
pp. 1656-1663 ◽  
Author(s):  
S. Yu. Ketkov



1970 ◽  
Vol 24 (3) ◽  
pp. 344-347 ◽  
Author(s):  
R. Ammini Amma ◽  
S. N. Thakur ◽  
K. P. R. Nair

The ir spectrum of isoquinoline has been investigated in the region 700–4000 cm−1. The observed frequencies have been correlated to the Raman frequencies and assigned to different modes of vibrations. The electronic absorption spectrum of the molecule has also been recorded in vapor phase in the region 2900–3200 Å. The system has been assigned to n–π* transition with the electronic origin at 31 984 cm−1. A vibrational analysis for the system is proposed.



2009 ◽  
Vol 74 (5) ◽  
pp. 1084-1089 ◽  
Author(s):  
Jin-Ling Song ◽  
Li-Ming Gong ◽  
Shou-Ai Feng ◽  
Jiang-Hong Zhao ◽  
Jian-Feng Zheng ◽  
...  


An electronic absorption spectrum, attributed to phenyl, has been observed in the visible region with origin at 18 908 cm -1 after flash photolysis of benzene and halogenobenzenes. Similar spectra of fluoro, chloro and bromo phenyl are observed after flash photolysis of disubstituted benzenes. The vibrational structure of the phenyl spectrum has been analysed in terms of two fundamental frequencies at 571 and 896 cm -1 which correspond to the e 2 g and a 1 g frequencies of the B 2 u state of benzene. The ground state of phenyl has a π 6 n electronic configuration and the observed transition is interpreted as 2 A 1 → 2 B 1 resulting from a π → n excitation.





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