Photoinduced interconversion ofcis- andtrans-isomers of bis(1,1,1-trifluoro-5,5-dimethyl-2,4-hexadionato)platinum(ii) studied by dynamic NMR spectroscopy

1997 ◽  
Vol 46 (5) ◽  
pp. 1038-1039 ◽  
Author(s):  
S. P. Babailov ◽  
Yu. G. Kriger ◽  
E. F. Reznikova ◽  
I. K. Igumenov

1982 ◽  
Vol 37 (2) ◽  
pp. 234-235 ◽  
Author(s):  
Rudy Susilo ◽  
Rolf Gmelin

Abstract The conformation of 1,2,4,5-tetrathian was determined by means of dynamic NMR spectroscopy. The barrier (ilG+) of the chair/twist equilibration is 14.5 kcal/mol and the chair form is more stable than the twist form in this molecule by 1.4 kcal/mol. These experimental data are in excellent agreement with force field calculations



Author(s):  
V. I. Bakhmutov ◽  
V. A. Burmistrov ◽  
K. K. Babievskii ◽  
�. I. Fedin ◽  
V. M. Belikov






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