Synthesis and characterization of cationic silsesquioxane hybrids by hydrolytic condensation of triethoxysilane derived from 2-(dimethylamino)ethyl acrylate

2012 ◽  
Vol 290 (18) ◽  
pp. 1879-1891 ◽  
Author(s):  
Hideharu Mori ◽  
Masato Yamada
Keyword(s):  
Ethyl Acrylate ◽  
Synthesis And Characterization ◽  
Hydrolytic Condensation

Synthesis of Novel Triazole-Containing Phosphonate Polymers

2015 ◽  
Vol 68 (4) ◽  
pp. 680 ◽  
Author(s):  
Ciarán Dolan ◽  
Briar Naysmith ◽  
Simon F. R. Hinkley ◽  
Ian M. Sims ◽  
Margaret A. Brimble ◽  
...  
Keyword(s):  
Chain Transfer ◽  
Click Reaction ◽  
Raft Polymerization ◽  
Ethyl Acrylate ◽  
Polymer Chemistry ◽  
Synthesis And Characterization ◽  
Reversible Addition

The objective of this research was to develop novel phosphonate-containing polymers as they remain a relatively under researched area of polymer chemistry. Herein, we report the synthesis and characterization of 2-(1-(2-(diethoxyphosphoryl)ethyl)-1H-1,2,3-triazol-4-yl)ethyl acrylate (M1) and diethyl (2-(4-(2-acrylamidoethyl)-1H-1,2,3-triazol-1-yl)ethyl)phosphonate (M2) monomers using the copper-catalyzed azide–alkyne cycloaddition (CuAAC) ‘click’ reaction, and their subsequent polymerization via both uncontrolled and reversible addition–fragmentation chain transfer (RAFT) polymerization techniques yielding phosphonate polymers (P1–P4).

Synthesis of Novel Triazole-Containing Phosphonate Polymers

2020 ◽  
Author(s):  
C Dolan ◽  
B Naysmith ◽  
Simon Hinkley ◽  
Ian Sims ◽  
MA Brimble ◽  
...  
Keyword(s):  
Chain Transfer ◽  
Click Reaction ◽  
Raft Polymerization ◽  
Ethyl Acrylate ◽  
Polymer Chemistry ◽  
Synthesis And Characterization ◽  
Reversible Addition

© 2015 CSIRO. The objective of this research was to develop novel phosphonate-containing polymers as they remain a relatively under researched area of polymer chemistry. Herein, we report the synthesis and characterization of 2-(1-(2-(diethoxyphosphoryl)ethyl)-1H-1,2,3-triazol-4-yl)ethyl acrylate (M1) and diethyl (2-(4-(2-acrylamidoethyl)-1H-1,2,3-triazol-1-yl)ethyl)phosphonate (M2) monomers using the copper-catalyzed azide-alkyne cycloaddition (CuAAC) 'click' reaction, and their subsequent polymerization via both uncontrolled and reversible addition-fragmentation chain transfer (RAFT) polymerization techniques yielding phosphonate polymers (P1-P4).

Synthesis and Characterization of Poly Methyl Acrylate-Poly Ethyl Acrylate Copolymer

1997 ◽  
Vol 35 (1-4) ◽  
pp. 119-128 ◽  
Author(s):  
C. León ◽  
R. Rodriguez ◽  
R. Peralta ◽  
C. Alvarez ◽  
V. M. Castaño
Keyword(s):  
Methyl Acrylate ◽  
Ethyl Acrylate ◽  
Synthesis And Characterization ◽  
Acrylate Copolymer
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