Rare earth element mobility during prograde granulite facies metamorphism: significance of fluorine

1996 ◽  
Vol 123 (3) ◽  
pp. 251-262 ◽  
Author(s):  
Y. Pan ◽  
Michael E. Fleet
Solid Earth ◽  
2020 ◽  
Vol 11 (6) ◽  
pp. 2303-2325
Author(s):  
José Manuel Benítez-Pérez ◽  
Pedro Castiñeiras ◽  
Juan Gómez-Barreiro ◽  
José R. Martínez Catalán ◽  
Andrew Kylander-Clark ◽  
...  

Abstract. The Sobrado unit, within the upper part of the Órdenes Complex (NW Spain) represents an allochthonous tectonic slice of exhumed high-grade metamorphic rocks formed during a complex sequence of orogenic processes in the middle to lower crust. In order to constrain those processes, U–Pb geochronology and rare-earth element (REE) analyses of accessory minerals in migmatitic paragneiss (monazite, zircon) and mylonitic amphibolites (titanite) were conducted using laser ablation split stream inductively coupled plasma mass spectrometry (LASS-ICP-MS). The youngest metamorphic zircon age obtained coincides with a Middle Devonian concordia monazite age (∼380 Ma) and is interpreted to represent the minimum age of the Sobrado high-P granulite facies metamorphism that occurred during the early stages of the Variscan orogeny. Metamorphic titanite from the mylonitic amphibolites yield a Late Devonian age (∼365 Ma) and track the progressive exhumation of the Sobrado unit. In zircon, cathodoluminescence images and REE analyses allow two aliquots with different origins in the paragneiss to be distinguished. An Early Ordovician age (∼490 Ma) was obtained for metamorphic zircons, although with a large dispersion, related to the evolution of the rock. This age is considered to mark the onset of granulite facies metamorphism in the Sobrado unit under intermediate-P conditions, and related to intrusive magmatism and coeval burial in a magmatic arc setting. A maximum depositional age for the Sobrado unit is established in the late Cambrian (∼511 Ma). The zircon dataset also record several inherited populations. The youngest cogenetic set of zircons yields crystallization ages of 546 and 526 Ma which are thought to be related to the peri-Gondwanan magmatic arc. The additional presence of inherited zircons older than 1000 Ma is interpreted as suggesting a West African Craton provenance.


2020 ◽  
Vol 6 (41) ◽  
pp. eabb6570 ◽  
Author(s):  
Michael Anenburg ◽  
John A. Mavrogenes ◽  
Corinne Frigo ◽  
Frances Wall

Carbonatites and associated rocks are the main source of rare earth elements (REEs), metals essential to modern technologies. REE mineralization occurs in hydrothermal assemblages within or near carbonatites, suggesting aqueous transport of REE. We conducted experiments from 1200°C and 1.5 GPa to 200°C and 0.2 GPa using light (La) and heavy (Dy) REE, crystallizing fluorapatite intergrown with calcite through dolomite to ankerite. All experiments contained solutions with anions previously thought to mobilize REE (chloride, fluoride, and carbonate), but REEs were extensively soluble only when alkalis were present. Dysprosium was more soluble than lanthanum when alkali complexed. Addition of silica either traps REE in early crystallizing apatite or negates solubility increases by immobilizing alkalis in silicates. Anionic species such as halogens and carbonates are not sufficient for REE mobility. Additional complexing with alkalis is required for substantial REE transport in and around carbonatites as a precursor for economic grade-mineralization.


Nature ◽  
1979 ◽  
Vol 282 (5736) ◽  
pp. 247-250 ◽  
Author(s):  
Scott M. McLennan ◽  
S. R. Taylor

Sign in / Sign up

Export Citation Format

Share Document