High-loading Pt nanoparticles on mesoporous carbon with large mesopores for highly active methanol electro-oxidation

2016 ◽  
Vol 20 (6) ◽  
pp. 1705-1712 ◽  
Author(s):  
Chengwei Zhang ◽  
Gongkai Wang ◽  
Xin Zhang ◽  
Yongguang Zhang
Keyword(s):  
Mesoporous Carbon ◽  
Pt Nanoparticles ◽  
High Loading ◽  
Highly Active ◽  
Electro Oxidation ◽  
Large Mesopores

scholarly journals Pt Nanoparticles Loaded on W18O49 Nanocables–rGO Nanocomposite as a Highly Active and Durable Catalyst for Methanol Electro-Oxidation

ACS Omega ◽  
2018 ◽  
Vol 3 (12) ◽  
pp. 16850-16857 ◽  
Author(s):  
Yizhi Wang ◽  
Shuo Wang ◽  
Fan Li ◽  
Yan Wang ◽  
Huairuo Zhang ◽  
...  
Keyword(s):  
Pt Nanoparticles ◽  
Highly Active ◽  
Electro Oxidation

scholarly journals A highly active, stable and synergistic Pt nanoparticles/Mo2C nanotube catalyst for methanol electro-oxidation

2015 ◽  
Vol 7 (1) ◽  
pp. e153-e153 ◽  
Author(s):  
Kai Zhang ◽  
Wei Yang ◽  
Chao Ma ◽  
Yan Wang ◽  
Chunwen Sun ◽  
...  
Keyword(s):  
Pt Nanoparticles ◽  
Highly Active ◽  
Electro Oxidation

CTAB assisted microwave synthesis of ordered mesoporous carbon supported Pt nanoparticles for hydrogen electro-oxidation

2007 ◽  
Vol 52 (14) ◽  
pp. 4691-4695 ◽  
Author(s):  
Jian-Hua Zhou ◽  
Jian-Ping He ◽  
Ya-Jun Ji ◽  
Wang-Juan Dang ◽  
Xiao-Lei Liu ◽  
...  
Keyword(s):  
Microwave Synthesis ◽  
Mesoporous Carbon ◽  
Pt Nanoparticles ◽  
Ordered Mesoporous Carbon ◽  
Ordered Mesoporous ◽  
Electro Oxidation

scholarly journals Electron donation of non-oxide supports boosts O2 activation on nano-platinum catalysts

2021 ◽  
Vol 12 (1) ◽  
Author(s):  
Tao Gan ◽  
Jingxiu Yang ◽  
David Morris ◽  
Xuefeng Chu ◽  
Peng Zhang ◽  
...  
Keyword(s):  
Catalytic Oxidation ◽  
Pt Nanoparticles ◽  
Catalytic Performance ◽  
Nitrogen Vacancy ◽  
Innovative Strategy ◽  
Oxide Supports ◽  
Heterogeneous Catalytic ◽  
Highly Active ◽  
Electron Sink ◽  
Nitrogen Vacancies

AbstractActivation of O2 is a critical step in heterogeneous catalytic oxidation. Here, the concept of increased electron donors induced by nitrogen vacancy is adopted to propose an efficient strategy to develop highly active and stable catalysts for molecular O2 activation. Carbon nitride with nitrogen vacancies is prepared to serve as a support as well as electron sink to construct a synergistic catalyst with Pt nanoparticles. Extensive characterizations combined with the first-principles calculations reveal that nitrogen vacancies with excess electrons could effectively stabilize metallic Pt nanoparticles by strong p-d coupling. The Pt atoms and the dangling carbon atoms surround the vacancy can synergistically donate electrons to the antibonding orbital of the adsorbed O2. This synergistic catalyst shows great enhancement of catalytic performance and durability in toluene oxidation. The introduction of electron-rich non-oxide substrate is an innovative strategy to develop active Pt-based oxidation catalysts, which could be conceivably extended to a variety of metal-based catalysts for catalytic oxidation.

Noncovalently functionalized graphitic mesoporous carbon as a stable support of Pt nanoparticles for oxygen reduction

2010 ◽  
Vol 195 (7) ◽  
pp. 1805-1811 ◽  
Author(s):  
Yuyan Shao ◽  
Sheng Zhang ◽  
Rong Kou ◽  
Xiqing Wang ◽  
Chongmin Wang ◽  
...  
Keyword(s):  
Oxygen Reduction ◽  
Mesoporous Carbon ◽  
Pt Nanoparticles

Rapid synthesis of a PtRu nano-sponge with different surface compositions and performance evaluation for methanol electrooxidation

Nanoscale ◽  
2015 ◽  
Vol 7 (21) ◽  
pp. 9467-9471 ◽  
Author(s):  
Meiling Xiao ◽  
Ligang Feng ◽  
Jianbing Zhu ◽  
Changpeng Liu ◽  
Wei Xing
Keyword(s):  
Performance Evaluation ◽  
Electronic Effect ◽  
Catalyst System ◽  
Methanol Electrooxidation ◽  
Co Poisoning ◽  
Rapid Synthesis ◽  
Highly Active ◽  
Electro Oxidation ◽  
Pt Utilization ◽  
And Performance

A rapid strategy to synthesize a highly active PtRu alloy nano-sponge catalyst system for methanol electro-oxidation is presented. The greatly increased Pt utilization, anti-CO poisoning ability and electronic effect result from the porous nano-sponge structure.

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