Selective Conversion of Cellulose into Ethylene Glycol over Metal–Organic Framework-Derived Multifunctional Catalysts

2014 ◽  
Vol 144 (10) ◽  
pp. 1728-1734 ◽  
Author(s):  
Shengpei Wang ◽  
Jinzhu Chen ◽  
Limin Chen
2021 ◽  
Vol 10 (4) ◽  
pp. 27-38
Author(s):  
Ha Bui Thi Thanh ◽  
Duong Le Van ◽  
Duong Le Ngoc ◽  
Hung Ta Ngoc ◽  
Anh Nguyen Le ◽  
...  

HKUST-1 (MOF-199), a metal-organic framework material is synthesized from Cu(OH)2 and modified by Pt. The prepared catalysts were used to reduce 4-nitrophenol (4-NP) into 4-aminophenol (4-AP). Featured results of the catalysts by XRD, SEM, TEM, FTIR, BET, DTA/TGA... showed that metal modified process with reduced agent ethylene glycol had high efficiency, with modified yield up to 90 %. Under our experimental conditions, the catalysts based HKUST-1, containing Pt had high efficiency; conversion was greater than 93 % in reduced reaction of 4-NP. Thus, the catalyst sample contained 2% Pt was the most suitable for the reduction with conversion gained 99,4 % after 250s.


2016 ◽  
Vol 18 (9) ◽  
pp. 2900-2908 ◽  
Author(s):  
Fumin Zhang ◽  
Shuang Zheng ◽  
Qiang Xiao ◽  
Yijun Zhong ◽  
Weidong Zhu ◽  
...  

Ultrasmall palladium nanoparticles (1.5–2.5 nm) encapsulated within the highly porous and hydrothermally stable amine-functionalized metal–organic framework UiO-66 exhibit excellent catalytic activity for the selective conversion of vanillin to 2-methoxy-4-methylphenol.


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