scholarly journals On the Promoting Effects of Te and Nb in the Activity and Selectivity of M1 MoV-Oxides for Ethane Oxidative Dehydrogenation

2020 ◽  
Vol 63 (19-20) ◽  
pp. 1754-1764
Author(s):  
Daniel Melzer ◽  
Gerhard Mestl ◽  
Klaus Wanninger ◽  
Andreas Jentys ◽  
Maricruz Sanchez-Sanchez ◽  
...  

AbstractThe pathways of ethane oxidative dehydrogenation and total combustion have been elucidated for M1 phase type Mo–V oxide catalysts with different metal composition. The ethane oxidation mechanism is not affected by the presence of Te or Nb. Conversely, the selectivity is strongly affected by stoichiometry of M1 catalysts. This is attributed to the facile oxidation of ethene to COx upon formation of unselective VOx species in the absence of Te and Nb.

ACS Catalysis ◽  
2016 ◽  
Vol 6 (7) ◽  
pp. 4775-4781 ◽  
Author(s):  
Mimoun Aouine ◽  
Thierry Epicier ◽  
Jean-Marc M. Millet

2016 ◽  
Vol 128 (31) ◽  
pp. 8914-8914
Author(s):  
Daniel Melzer ◽  
Pinghong Xu ◽  
Daniela Hartmann ◽  
Yuanyuan Zhu ◽  
Nigel D. Browning ◽  
...  

2016 ◽  
Vol 128 (31) ◽  
pp. 9019-9023 ◽  
Author(s):  
Daniel Melzer ◽  
Pinghong Xu ◽  
Daniela Hartmann ◽  
Yuanyuan Zhu ◽  
Nigel D. Browning ◽  
...  

2002 ◽  
Vol 106 (21) ◽  
pp. 5421-5427 ◽  
Author(s):  
Morris D. Argyle ◽  
Kaidong Chen ◽  
Alexis T. Bell ◽  
Enrique Iglesia

2016 ◽  
Vol 55 (31) ◽  
pp. 8873-8877 ◽  
Author(s):  
Daniel Melzer ◽  
Pinghong Xu ◽  
Daniela Hartmann ◽  
Yuanyuan Zhu ◽  
Nigel D. Browning ◽  
...  

2020 ◽  
Author(s):  
Leelavathi Annamalai ◽  
Sopuruchukwu Ezenwa ◽  
Yanliu Dang ◽  
Haiyan Tan ◽  
Steven L. Suib ◽  
...  

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