From the Kissinger equation to model-free kinetics: reaction kinetics of thermally initiated solid-state reactions

ChemTexts ◽  
2018 ◽  
Vol 4 (3) ◽  
Author(s):  
Henrik Schulz
Keyword(s):  
Solid State ◽  
Reaction Kinetics ◽  
Solid State Reactions ◽  
Kissinger Equation ◽  
Model Free ◽  
Model Free Kinetics ◽  
Kinetics Of

White Beam Synchrotron Topographic Studies of the Effects of Localized Stress Fields on the Kinetics of Single Crystal Solid State Reactions.

1988 ◽  
Vol 143 ◽  
Author(s):  
Michael Dudley
Keyword(s):  
Solid State ◽  
Reaction Kinetics ◽  
Local Reaction ◽  
Stress Fields ◽  
Solid State Reactions ◽  
Thermally Induced ◽  
White Beam ◽  
Kinetics Of ◽  
Good Agreement

AbstractWhite Beam Synchrotron Topography has been used to determine the role of localized stress fields in the solid state polymerization of single crystals of the diacetylene PTS. Results indicate that the stress fields due to grown in dislocations can accelerate local reaction kinetics in thermally induced polymerization reactions, although no such effects were previously observable in photolytically or radiolytically induced reactions. Results are analyzed in an analogous fashion to the treatment of the nucleation of solid state phase transformations at dislocations. Good agreement was found between approximate theoretical treatments and experimental observation. The response of the monomer crystal to the inhomogeneous stresses generated as a result of inhomogeneous reaction and the implications regarding local reaction kinetics are discussed in detail.

scholarly journals Kinetics of Solid State Reactions in 2FeO–SiO2 and 2NiO–SiO2 Systems

1985 ◽  
Vol 26 (8) ◽  
pp. 542-548
Author(s):  
Masayasu Kawahara ◽  
Toshiharu Mitsuo ◽  
Yoshinori Shirane
Keyword(s):  
Solid State ◽  
Solid State Reactions ◽  
Kinetics Of
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