Properties of phosphate glass waste forms containing fluorides from a molten salt reactor

2016 ◽  
Vol 27 (3) ◽  
Author(s):  
Ya-Ping Sun ◽  
Xiao-Bin Xia ◽  
Yan-Bo Qiao ◽  
Zhong-Qi Zhao ◽  
Hong-Jun Ma ◽  
...  
2002 ◽  
Vol 757 ◽  
Author(s):  
K. Sun ◽  
L. M. Wang ◽  
R. C. Ewing

ABSTRACTA series of iron phosphate glass waste forms with compositions of 45Fe2O3-55P2O5, 20Fe2O3-80P2O5, and 20Fe2O3-20Na2O-60P2O5, namely FeP-1, FeP-2 and FeP-3, was studied by analytical electron microscopy (AEM). Transmission electron microscopy (TEM) bright-field (BF) imaging showed that under the electron irradiation, phase segregation occurred in both the FeP-1 and FeP-2 samples at high electron doses (3.84×1026 e/m2). In contrast, bubbles formed in the FeP-3 sample, even at a relatively low dose (2.88×1025 e/m2), which may be attributed to the migration of Na under irradiation as in the case in sodium borosilicate glass. Series electron energy-loss spectroscopy (EELS) analysis showed that the glass materials experienced mass-loss and composition variation. No obvious Fe valence state changes under irradiation were observed within the irradiation period.


2017 ◽  
Vol 458 ◽  
pp. 149-156 ◽  
Author(s):  
Chandra S. Ray ◽  
V.A. Samaranayake ◽  
Ali Mohammadkhah ◽  
Thomas E. Day ◽  
Delbert E. Day

2018 ◽  
Vol 495 ◽  
pp. 107-116 ◽  
Author(s):  
Chandra S. Ray ◽  
V.A. Samaranayake ◽  
Ali Mohammadkhah ◽  
Thomas E. Day ◽  
Delbert E. Day

1988 ◽  
Vol 25 (8) ◽  
pp. 661-666 ◽  
Author(s):  
Tadashi YANAGI ◽  
Makoto YOSHIZOE ◽  
Naoki NAKATSUKA

1989 ◽  
Vol 26 (10) ◽  
pp. 948-954 ◽  
Author(s):  
Tadashi YANAGI ◽  
Makoto YOSHIZOE ◽  
Ken-ichi KURAMOTO

2018 ◽  
Author(s):  
Rebecca M. Chamberlin ◽  
Ming Tang ◽  
Rosendo Borjas Nevarez ◽  
Gordon Dennis Jarvinen ◽  
Daniel Koury ◽  
...  

2021 ◽  
Vol 160 ◽  
pp. 108370
Author(s):  
Alexander M. Wheeler ◽  
Ondřej Chvála ◽  
Steven Skutnik

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