A multifluid corresponding states principle for the thermodynamic properties of fluid mixtures

1982 ◽  
Vol 37 (5) ◽  
pp. 799 ◽  
Author(s):  
Josef P. Novák ◽  
Vlastimil Růžička
Keyword(s):  
Thermodynamic Properties ◽  
Corresponding States ◽  
Fluid Mixtures ◽  
Corresponding States Principle

Thermodynamic properties of dense fluid mixtures

1967 ◽  
Vol 45 (6) ◽  
pp. 595-604 ◽  
Author(s):  
M. Orentlicher ◽  
J. M. Prausnitz
Keyword(s):  
Experimental Data ◽  
Thermodynamic Properties ◽  
Hard Sphere ◽  
Simple Fluids ◽  
Fluid Mixtures ◽  
Functional Expansion ◽  
Residual Properties ◽  
Dense Fluid ◽  
Liquid Solutions ◽  
Point Of Departure

By using the properties of hard-sphere systems as a point of departure, equations are derived for the residual properties of mixtures of real simple fluids at liquid-like densities. The essence of the derivation lies in a functional expansion of g(r) exp [Formula: see text] about its hard-sphere value. The results obtained are useful for interpreting, correlating, and extending experimental data for both concentrated and dilute liquid solutions.

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