Resonance Raman spectra and excited-state geometry of the radical cation of p-dichlorobenzene

1989 ◽  
Vol 164 (4) ◽  
pp. 388-394 ◽  
Author(s):  
Tatsuhisa Kato ◽  
Naoki Muraki ◽  
Tadamasa Shida
Keyword(s):  
Excited State ◽  
Raman Spectra ◽  
Radical Cation ◽  
Resonance Raman ◽  
Resonance Raman Spectra

scholarly journals Structure of the triplet excited state of bromanil from time-resolved resonance Raman spectra and simulation

2001 ◽  
Vol 115 (13) ◽  
pp. 6106-6114 ◽  
Author(s):  
Mrinalini Puranik ◽  
Siva Umapathy ◽  
Jaap G. Snijders ◽  
Jayaraman Chandrasekhar
Keyword(s):  
Excited State ◽  
Raman Spectra ◽  
Resonance Raman ◽  
Triplet Excited State ◽  
Time Resolved ◽  
Resonance Raman Spectra

scholarly journals Accurate Assignments of Excited-State Resonance Raman Spectra: A Benchmark Study Combining Experiment and Theory

2017 ◽  
Vol 121 (41) ◽  
pp. 7937-7946 ◽  
Author(s):  
Matthew S. Barclay ◽  
Timothy J. Quincy ◽  
David B. Williams-Young ◽  
Marco Caricato ◽  
Christopher G. Elles
Keyword(s):  
Excited State ◽  
Raman Spectra ◽  
Resonance Raman ◽  
Benchmark Study ◽  
State Resonance ◽  
Resonance Raman Spectra

Infrared absorption and resonance Raman scattering of photochromic triphenylformazans

1983 ◽  
Vol 61 (5) ◽  
pp. 809-816 ◽  
Author(s):  
J. W. Lewis ◽  
C. Sandorfy
Keyword(s):  
Excited State ◽  
Raman Scattering ◽  
Proton Transfer ◽  
Raman Spectra ◽  
Infrared Absorption ◽  
Resonance Raman ◽  
Tautomeric Equilibrium ◽  
Resonance Raman Scattering ◽  
Excited State Proton Transfer ◽  
Resonance Raman Spectra

The infrared and resonance Raman spectra of the two long-lived forms of triphenylformazan and several of its derivatives have been examined. The spectra of unsymmetrically 15N-labelled derivatives suggest that two tautomers exist for each of the two forms. This observation is confirmed by the spectra of 1-(p-halophenyl)-3,5-diphenylformazans. The spectra of the non-chelate forms of these latter compounds demonstrate that the position of the tautomeric equilibrium is influenced by the electron-attracting ability of the para-halo-substituent. A comparison of the resonance Raman spectra of the two forms leads to the conclusion that excited state proton transfer is the initial photoevent in the photochromism of the triphenylformazans.

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