An irreversible thermodynamic model for cell freezing with cryophylactic additives

Cryobiology ◽  
1979 ◽  
Vol 16 (6) ◽  
pp. 590-591
Author(s):  
M.E. Lynch ◽  
K.R. Diller
Author(s):  
Pedro J Fito ◽  
Juan Angel Tomas-Egea ◽  
Marta Castro-Giraldez

Food dehydration is one of a main process to preserve meal. In order to optimaze a freeze-drying operation a physic model is needed to well describe the thermodynamic behaviors involved in this process. In this work, a thermographic camera and different physico-chemical determinations are used to monitor many phenomena that occur during the lyophilization of poultry breast. Finally, a non-continuous irreversible thermodynamic model, based on thermal infrared measures and in shrinkage/swelling mechanism, has been developed, wich explains the behaviours produced throughout the meat freeze-drying process. Keywords: freeze-drying, thermodynamic model, infrared thermography, poultry.


1986 ◽  
Vol 50 (357) ◽  
pp. 427-439 ◽  
Author(s):  
C. T. Foster

AbstractTextures produced by reactions involving garnet in a sillimanite-staurolite schist have been investigated using an irreversible thermodynamic model. The model predicts that the local production or consumption of garnet is strongly influenced by the proximity of garnet to growing sillimanite and dissolving staurolite. Garnets within sillimanite segregations should dissolve near the sillimanite-bearing centre of the segregation while garnets within or adjacent to staurolite poikilo-blasts should grow as the staurolite is replaced by a muscovite-rich pseudomorph. Garnets located in the matrix may grow, not react at all, or dissolve depending on the local configuration of nearby sillimanite, staurolite, and garnet. Textures predicted by the model are similar to those observed in thin section: many garnets are truncated within sillimanite segregations; garnets located in pseudo-morphs after staurolite are equant and have thick unpoikilitic rims that suggest growth; most matrix garnets also have thick inclusion-free rims that suggest growth but a few have thin rims, indicating little growth, or are irregularly shaped, suggesting dissolution.


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