Radical polymerization in halogenated solvents—II. Methyl methacrylate polymerization initiated by benzoyl peroxide

1969 ◽  
Vol 5 (1) ◽  
pp. 231-237 ◽  
Author(s):  
G.M. Burnett ◽  
G.G. Cameron ◽  
Brenda M. Parker
Keyword(s):  
Methyl Methacrylate ◽  
Benzoyl Peroxide ◽  
Radical Polymerization ◽  
Methyl Methacrylate Polymerization ◽  
Halogenated Solvents

scholarly journals Effect of Ferocene Concentration on the Percent Conversion and Molecular Weight of Poly(Methyl Methacrylate) Homopolymers

2017 ◽  
Vol 14 (2) ◽  
pp. 311-319
Author(s):  
Baghdad Science Journal
Keyword(s):  
Molecular Weight ◽  
Free Radical ◽  
Methyl Methacrylate ◽  
Benzoyl Peroxide ◽  
Radical Polymerization ◽  
Free Oxygen ◽  
Poly Methyl Methacrylate ◽  
Methacrylate Monomer ◽  
Percent Conversion ◽  
Methyl Methacrylate Monomer

This research is addressing the effect of different ferrocene concentration (0.00, 2.15x10-3, 4.30x10-3, 8.60x10-3, and 12.9x10-3) on the bulk free radical polymerization of methyl methacrylate monomer in benzene using benzoyl peroxide as initiator. The polymerization was conducted at 60º C under free oxygen atmosphere. The resulting polymers were characterized by FTIR. The results were compared with the presence and absence of ferrocene at 10% conversion. The %conversion was 3.04% with no ferrocene present in the polymerization medium and its increase to 9.06 with a first lowest ferrocene concentration added, i.e. 2.15 x10-3mol/l. This was positively reflected on the poly(methyl methacrylate) molecular weight measured by viscosity technique, especially in the presence of ferrocene.

Radical polymerization of methyl methacrylate in the presence of benzoyl peroxide, ferrocene and zirconocene dichloride

2011 ◽  
Vol 21 (4) ◽  
pp. 206-208 ◽  
Author(s):  
Yurii B. Monakov ◽  
Regina M. Islamova ◽  
Anna K. Frizen ◽  
Olesya I. Golovochesova ◽  
Svetlana V. Nazarova
Keyword(s):  
Methyl Methacrylate ◽  
Benzoyl Peroxide ◽  
Radical Polymerization ◽  
Zirconocene Dichloride

Radical polymerization of methyl methacrylate in the presence of benzoyl peroxide, ferrocene and zirconocene dichloride

2012 ◽  
Vol 22 (1) ◽  
pp. 55
Author(s):  
Yurii B. Monakov ◽  
Regina M. Islamova ◽  
Anna K. Frizen ◽  
Olesya I. Golovochesova ◽  
Svetlana V. Nazarova
Keyword(s):  
Methyl Methacrylate ◽  
Benzoyl Peroxide ◽  
Radical Polymerization ◽  
Zirconocene Dichloride
Sign in / Sign up

Export Citation Format

Share Document