High-resolution fourier transform spectra and rotational analysis of monoisotopic H3Si79Br in the ν2, ν5 region near 900 cm−1

1984 ◽  
Vol 108 (2) ◽  
pp. 215-229 ◽  
Author(s):  
H. Bürger ◽  
H. Beckers ◽  
J. Kauppinen
Keyword(s):  
Fourier Transform ◽  
High Resolution ◽  
Rotational Analysis ◽  
Fourier Transform Spectra

Rotational analysis of the 13 200 and 13 400 cm−1 bands of NO2 by means of Fourier transform spectroscopy

1982 ◽  
Vol 60 (9) ◽  
pp. 1288-1302 ◽  
Author(s):  
A. Perrin ◽  
J. -M. Flaud ◽  
C. Camy-Peyret ◽  
P. Luc
Keyword(s):  
Fourier Transform ◽  
High Resolution ◽  
Ground State ◽  
Electronic Transition ◽  
Spin Orbit ◽  
Rotational Analysis ◽  
Coriolis Coupling ◽  
Absorption Bands ◽  
Vibrational Assignments ◽  
Fourier Transform Spectra

The analysis of two parallel absorption bands of NO2, at 13 400 and 13 200 cm−1 respectively, has been performed using high resolution Fourier transform spectra. This paper is an extension of the work performed on the 7390 Å band (13 500 cm−1) in 1977 by Hallin and Merer, and completed in 1980 by Perrin, Camy-Peyret, Flaud, and Luc.The lines involving the Ka = 0, 1, 2, 3, 4 stacks for the 13 400 cm−1 band and Ka = 0, 1, 3, 4 for the 13 200 cm−1 band have been assigned and considerable spin–orbit and/or Coriolis coupling induced transitions have been detected.The 13 400 cm−1 band can be considered as belonging to the [Formula: see text] electronic transition, while the 13 200 cm−1 band might be, as the 7390 Å band (at 13 500 cm−1), a transition within the ground state manifold which barrows its intensity through vibronic coupling from the 13 400 cm−1 band. Tentative vibrational assignments are given.

Ground state molecular parameters of phosphine, PH3, from the simultaneous analysis of the high-resolution infrared, microwave and submillimeterwave spectra

1985 ◽  
Vol 50 (11) ◽  
pp. 2480-2492 ◽  
Author(s):  
Soňa Přádná ◽  
Dušan Papoušek ◽  
Jyrki Kauppinen ◽  
Sergei P. Belov ◽  
Andrei F. Krupnov ◽  
...  
Keyword(s):  
Fourier Transform ◽  
High Resolution ◽  
Ground State ◽  
Unitary Transformation ◽  
Point Of View ◽  
Acoustic Detection ◽  
Molecular Parameters ◽  
Microwave Spectrometer ◽  
Fourier Transform Spectra ◽  
First Time

Fourier transform spectra of the ν2 band of PH3 have been remeasured with 0.0045 cm-1 resolution. Ground state combination differences from these data have been fitted simultaneously with the microwave and submillimeterwave data to determine the ground state spectroscopical parameters of PH3 including the parameters of the Δk = ± 3n interactions. The correlation between the latter parameters has been discussed from the point of view of the existence of two equivalent effective rotational operators which are related by a unitary transformation. The ΔJ = 0, +1, ΔK = 0 (A1 ↔ A2, E ↔ E) rotational transitions in the ν2 and ν4 states have been measured for the first time by using a microwave spectrometer and a radiofrequency spectrometer with acoustic detection.

High-Resolution Fourier Transform Spectra of HDSe: The Interacting States (v1v2v3)/(v1 ± 1 v2 ∓ 2 v3) with 2v1 + v2 = 1, 2, 3, and 4

2000 ◽  
Vol 202 (2) ◽  
pp. 229-248 ◽  
Author(s):  
O.N. Ulenikov ◽  
H. Bürger ◽  
W. Jerzembeck ◽  
G.A. Onopenko ◽  
E.A. Zhabina ◽  
...  
Keyword(s):  
Fourier Transform ◽  
High Resolution ◽  
Fourier Transform Spectra

ChemInform Abstract: High-Resolution Fourier Transform Spectra of CH2D2: The Fermi- Interacting Vibrational Bands ν8(B2), ν4 + ν9(B2) and 2ν9( A1), ν3 + ν4(A1).

ChemInform ◽  
2010 ◽  
Vol 22 (46) ◽  
pp. no-no
Author(s):  
O. N. ULENIKOV ◽  
A. B. MALIKOVA ◽  
G. A. SHEVCHENKO ◽  
G. GUELACHVILI ◽  
M. MORILLON-CHAPEY
Keyword(s):  
Fourier Transform ◽  
High Resolution ◽  
Vibrational Bands ◽  
Fourier Transform Spectra

High-Resolution Fourier Transform Spectra of AsH3: The Vibrational Bands 2ν2(A1), ν2 + ν4(E), ν1(A1), and ν3(E)

1993 ◽  
Vol 157 (1) ◽  
pp. 141-160 ◽  
Author(s):  
O.N. Ulenikov ◽  
A.E. Cheglokov ◽  
G.A. Shevchenko ◽  
M. Winnewisser ◽  
B.P. Winnewisser
Keyword(s):  
Fourier Transform ◽  
High Resolution ◽  
Vibrational Bands ◽  
Fourier Transform Spectra

The absorption spectrum of C2H2 around ν1 + ν3: energy standards in the 1.5 μm region and vibrational clustering

1994 ◽  
Vol 72 (11-12) ◽  
pp. 1241-1250 ◽  
Author(s):  
Q. Kou ◽  
G. Guelachvili ◽  
M. Abbouti Temsamani ◽  
M. Herman
Keyword(s):  
Absorption Spectrum ◽  
Fourier Transform ◽  
High Resolution ◽  
Rotational Analysis ◽  
Vibrational Assignment ◽  
Calibration Standards ◽  
Vibrational Levels ◽  
Vibrational Transitions ◽  
The Fourier Transform ◽  
Anharmonic Couplings

We have recorded the Fourier transform absorption spectrum of acetylene, C2H2, at high resolution, around 6500 cm−1. The positions of the strongest rovibrational lines are measured with respect to the rovibrational lines in 3-0 of CO. They provide secondary calibration standards in that range with an accuracy of 3 × 10−4 cm−1. The rotational analysis of the data gives evidence of five vibrational levels of [Formula: see text] symmetry, in addition to the bright combination level (1010000). This is demonstrated to strictly fit the predicted anharmonic resonance pattern in that region, which permits the vibrational assignment of those extra transitions. Study of the relative intensities of the reported vibrational transitions suggests the need to include new quartic anharmonic couplings. This is supported by the rovibrational analysis of the cold bands around 8500 cm−1, involving the (1110000) bright level, which is also presented.

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