Lone-pair ligand effects on the oxidative addition of methane to second-row transition metal complexes

1995 ◽  
Vol 491 (1-2) ◽  
pp. 231-245 ◽  
Author(s):  
Per E.M. Siegbahn
Keyword(s):  
Transition Metal ◽  
Metal Complexes ◽  
Transition Metal Complexes ◽  
Oxidative Addition ◽  
Lone Pair ◽  
Ligand Effects

Transition Metal Complexes of Diazenes, XVII [1]. Reactions of 1,2-Diazetines and 1,2-Diazetine-N-oxides with Iron Carbonyls

1982 ◽  
Vol 37 (4) ◽  
pp. 463-467 ◽  
Author(s):  
A. Albini ◽  
H. Kisch ◽  
C. Krüger ◽  
An-Pei Chiang
Keyword(s):  
Molecular Structure ◽  
Transition Metal ◽  
Metal Complexes ◽  
Electronic Properties ◽  
Transition Metal Complexes ◽  
Lone Pair ◽  
X Ray ◽  
Iron Carbonyls

Enneacarbonyldiiron reacts with 3,3,4,4-tetramethyl-1,2-diazetine (L) or its mono-N-oxide (L′) to form complexes (L)Fe(CO)4 (3), (L)Fe2(CO)7 (4), (L)Fe2(CO)6 (5), or (L′)Fe(CO)4 (6), and small amounts of deoxygenated 4 and 5, respectively. Formation and stability of the complexes is compared with those of ligands with smaller and larger ring sizes and discussed in terms of the electronic properties of the ligand lone-pair Orbitals. The molecular structure of 4 is established by X-ray analysis.

Tandem transmetallation and oxidative addition reactions of [Sn(R)2(Ph2PC6H4-2-S)2] with transition metal complexes of the Group 9

2004 ◽  
Vol 689 (1) ◽  
pp. 174-180 ◽  
Author(s):  
Daniel Canseco-González ◽  
Valente Gómez-Benı́tez ◽  
Oscar Baldovino-Pantaleón ◽  
Simón Hernández-Ortega ◽  
David Morales-Morales
Keyword(s):  
Transition Metal ◽  
Metal Complexes ◽  
Transition Metal Complexes ◽  
Oxidative Addition ◽  
Addition Reactions

Oxidative addition of arylhydrazonoyl and benzylsulphonyl chlorides to transition metal complexes

1980 ◽  
Vol 194 (2) ◽  
pp. 211-220 ◽  
Author(s):  
Francesca Porta ◽  
Sergio Cenini ◽  
Paola Del Buttero ◽  
Stefano Maiorana
Keyword(s):  
Transition Metal ◽  
Metal Complexes ◽  
Transition Metal Complexes ◽  
Oxidative Addition
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