Polymer complexes. Part IV—Thermal stability of poly(8-quinolyl acrylate) and the polymers of the complexes of 8-quinolyl acrylate with some transition metal salts

1988 ◽  
Vol 22 (4) ◽  
pp. 295-302 ◽  
Author(s):  
A.Z. El-Sonbati ◽  
M.A. Diab
Keyword(s):  
Thermal Stability ◽  
Transition Metal ◽  
Metal Salts ◽  
Polymer Complexes ◽  
Transition Metal Salts ◽  
Thermal Stability Of

scholarly journals NITRILE COMPLEXES AS EFFECTIVE ANTIMICROBIAL ADDITIVES

2018 ◽  
Vol 59 (5) ◽  
pp. 81
Author(s):  
Ilnara I. Safiullina ◽  
Elbeiy R. Babaev ◽  
Rauliya R. Syrlybaeva ◽  
Nazrin Ch. Movsum-zade
Keyword(s):  
Transition Metal ◽  
Antimicrobial Properties ◽  
Mineral Oil ◽  
Metal Salts ◽  
Central Metal ◽  
Polymer Complexes ◽  
Metal Atoms ◽  
Transition Metal Salts ◽  
In Situ Copolymerization

Antimicrobial properties of nitrile complexes of transition metal salts were studied including the investigation of their activity in surfactants and mineral oil environments. Experiments of the polymeric complexes preparation by in-situ copolymerization of the nitrile polymers in the presence of transition metal salts and reactions of transition metal salts added to the ready polymers were performed. The dependence of the polymer complexes forming particularities on central metal atoms nature was determined.

scholarly journals THEORETICAL INVESTIGATION OF THERMODYNAMIC PARAMETERS OF TRANSITION METAL SALTS COMPLEXATION WITH ACRYLONITRILE-STYRENE COPOLYMER

2018 ◽  
Vol 59 (4) ◽  
pp. 14
Author(s):  
Il’nara I. Safiullina ◽  
Yuriy I. Puzin ◽  
Raulya R. Syrlybaeva ◽  
Yan Krivcik ◽  
Yana Morozova ◽  
...  
Keyword(s):  
Transition Metal ◽  
Thermodynamic Parameters ◽  
Chemical Processes ◽  
Metal Salts ◽  
Polymer Complexes ◽  
Formation Reaction ◽  
Transition Metal Salts ◽  
Complexes Of Transition Metals ◽  
Thermodynamic Parameters Of Formation ◽  
Computational Level

Thermodynamic parameters of formation reactions of polymer complexes of transition metals (ZnCl2, CuCl2, NiCl2, СоС12) were obtained using the PBE96/SVP computational level. Chemical processes taking place during both direct copolymerizations in the presence of transition metal salts and at introduction of transition metal salts at final step of polymerization were considered. The success of formation reaction of polymer complexes was theoretically based with the radical polymerization into solutions of transition metal salts in the presence of zink chloride only. 

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