In situ FT—IR study of copper—chromium oxide catalysts in CO oxidation

1992 ◽  
Vol 74 (1-3) ◽  
pp. 193-205 ◽  
Author(s):  
Jowi W. Bijsterbosch ◽  
Freek Kapteijn ◽  
Jacob A. Moulijn
1963 ◽  
Vol 7 ◽  
pp. 229-239
Author(s):  
M. Stammler ◽  
M. Pyzyna

AbstractAn extensive investigation of chemical composition, particle size, and surface area of copper-chromium oxide catalysts has been made. The two phases present in the activated material are copper oxide (CuO) and copper-chromium spinel (CuCr2O4). The crystallite size of the CuO phase (determined by X-ray diffraction line broadening) can be correlated with the catalytic activity measured on a CO-CO2 oxidation reaction. The catalytic activity of the oxide catalyst can be expressed as a function of the X-ray fluorescence intensity of the Cu Kα line even on changing the absolute copper concentration up to 3%. An attempt is made to explain this phenomenon by the heterogeneity effect caused by the difference in the linear absorption factors for the Cu Kα radiation in the system CuO-CuCr2O4.


1931 ◽  
Vol 53 (5) ◽  
pp. 2012-2012 ◽  
Author(s):  
Ralph. Connor ◽  
Karl. Folkers ◽  
Homer. Adkins

1932 ◽  
Vol 54 (3) ◽  
pp. 1138-1145 ◽  
Author(s):  
Ralph Connor ◽  
Karl Folkers ◽  
Homer Adkins

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