MOLECULAR REACTION DYNAMICS BY THE CROSSED MOLECULAR BEAM TECHNIQUE: A FEW RECENT EXAMPLES

1979 ◽  
pp. 781-783
Author(s):  
Richard B. Bernstein
Keyword(s):  
Molecular Beam ◽  
Reaction Dynamics ◽  
Molecular Reaction ◽  
Beam Technique ◽  
Crossed Molecular Beam

scholarly journals Reaction dynamics of the 4-methylphenyl radical (C6H4CH3; p-tolyl) with isoprene (C5H8) – formation of dimethyldihydronaphthalenes

2014 ◽  
Vol 16 (31) ◽  
pp. 16805-16814 ◽  
Author(s):  
Beni B. Dangi ◽  
Tao Yang ◽  
Ralf I. Kaiser ◽  
Alexander M. Mebel
Keyword(s):  
Electronic Structure ◽  
Molecular Beam ◽  
Collision Energy ◽  
Reaction Dynamics ◽  
Electronic Structure Calculations ◽  
Single Collision ◽  
Collision Condition ◽  
Structure Calculations ◽  
Beam Technique ◽  
Crossed Molecular Beam

Reaction dynamics and energetics of 4-methylphenyl radical with isoprene are reported under single collision condition at collision energy of 58 kJ mol−1 by exploiting the crossed molecular beam technique and electronic structure calculations.

Reaction Dynamics of O(3P) + Propyne: I. Primary Products, Branching Ratios, and Role of Intersystem Crossing from Crossed Molecular Beam Experiments

2016 ◽  
Vol 120 (27) ◽  
pp. 4603-4618 ◽  
Author(s):  
Gianmarco Vanuzzo ◽  
Nadia Balucani ◽  
Francesca Leonori ◽  
Domenico Stranges ◽  
Vaclav Nevrly ◽  
...  
Keyword(s):  
Molecular Beam ◽  
Reaction Dynamics ◽  
Branching Ratios ◽  
Intersystem Crossing ◽  
Primary Products ◽  
Crossed Molecular Beam

scholarly journals Crossed Molecular Beam Experiments of Radical-Neutral Reactions Relevant to the Formation of Hydrogen Deficient Molecules in Extraterrestrial Environments

2000 ◽  
Vol 197 ◽  
pp. 251-264 ◽  
Author(s):  
R. I. Kaiser ◽  
N. Balucani ◽  
O. Asvany ◽  
Y. T. Lee
Keyword(s):  
Laboratory Experiments ◽  
Molecular Beam ◽  
Carbon Clusters ◽  
Reaction Products ◽  
Chemical Reaction Dynamics ◽  
Cyano Radical ◽  
First Time ◽  
Beam Technique ◽  
Collision Complexes ◽  
Crossed Molecular Beam

During the last 5 years, laboratory experiments relevant to the formation of carbon-bearing molecules in extraterrestrial environments have been performed employing the crossed molecular beam technique and a high intensity source of ground state atomic carbon, C(3Pj). These investigations unraveled for the first time detailed information on the chemical reaction dynamics, involved collision complexes and intermediates, and – most important – reaction products of neutral-neutral reactions. Here, we extend these studies even further, and report on very recent crossed beam experiments of cyano radical, CN(2Σ+), reactions with unsaturated hydrocarbons to form nitriles in extraterrestrial environments and Saturn's moon Titan. Further, preliminary results on reactions of small carbon clusters and with acetylene, ethylene, and methylacetylene to synthesize hydrogen-deficient carbon-bearing molecules are presented.

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