The results of the development of synthesis technique of cyclocarbinol derivatives of cymantrene and the production of relevant barium cyclocarbinolate metal complexes – new, advanced anti-smoke additives were presented. Comparative data on the anti-smoke effectiveness of synthesized compounds and known antismoke additives for diesel fuels were also presented. Established, results of the development of a single-stage synthesis method of cyclocarbinol derivatives of cymantrene can be assumed as a basic process for producing high-effective anti-smoke additives to diesel fuels that comply with the requirements of ecology in operation of diesel vehicles.