Visual turn as an interpretive model of stage synthesis of arts in the culture of the XX–XXI century

Visual turn as an interpretive model of stage synthesis of arts in the culture of the XX–XXI century Purpose of the Article. The research is related to the definition of visual and virtual dimensions of the interpretation of fashion activity as a certain communicative scene. The research methodology is to apply a retrospective analysis of visual patterns in the stage space of everyday culture. The scientific novelty of the work is that the scene is perceived by the recipient as an optical phenomenon, has a wide space in which the actor of action or event performs certain communicative acts verbally and optically. The components of this synthesis plastically, gesturally, verbally-dramatically and optically-visually present a whole selection of arts that form a stage synthesis. Drama is verbalized as a plastic behavior, where the action, movements determine the high space of mise-en-scène of the tank, which testifies to both the expressive arts known since ancient Greek chorea and the visual-optical patterns. Thus, in the context of visual rotation, ocular centrism is actualized - trust in the picture. Conclusions. It should be noted that there is an artistic critique of the media, producers, galleries, magazines, that is, a space of unification and adequate representation of various art phenomena is formed. It is not the artists themselves, the actors of the big stage, the producers of the great culture of everyday life who live a full life, but those who create art events, local scenes of the presentation. Visual research tends to eclecticism, which turns into a polymorphic set of discourses, which indicates that you need to find a comfort zone, certain attractions of everyday culture. Without them, the realization of a modern art product is no longer possible. Advertising management, imageology are presented in society as an indirect reality, similar to virtual technology. Imagination as a video presentation becomes a problem of interpretation, a problem of vision. Visual culture tries to rehabilitate the image and determine its meaning without a name, without a name. Such a culture without a name leads to the fact that researchers are beginning to determine only what has a name. Art history describes the relationships between objects, chronological order, movement, formal preferences, and iconographic data. Needless to say, the work of art in this case remains an individual creation, a special source of life, and a social text. The culture of everyday life in the context of visual rotation is simultaneously a text, an image, a stage artifact, a pattern, and a flash image. Key words: culture, culture of everyday life, stage synthesis of culture of everyday life, image, visual turn.

Tandem Synthesis of Ultra-High Molecular Weight Drag Reducing Poly-α-Olefins for Low-Temperature Pipeline Transportation

Ultra-high molecular weight poly-α-olefins are widely used as drag reducing agents (DRAs) for pipeline transportation of oil and refined petroleum products. The synthesis of polyolefin DRAs is based on low-temperature Ziegler–Natta (ZN) polymerization of higher α-olefins. 1-Hexene based DRAs, the most effective at room temperature, typically lose DR activity at low temperatures. The use of 1-hexene copolymers with C8–C12 linear α-olefins appears to offer a solution to the problem of low-temperature drag reducing. The present work aims to develop two-stage synthesis of polyolefin DRAs that is based on selective oligomerization of ethylene in the presence of efficient chromium/aminodiphosphine catalysts (Cr-PNP), followed by polymerization of the olefin mixtures, formed at oligomerization stage, using efficient titanium–magnesium ZN catalyst. We have shown that oligomerization of ethylene in α-olefin reaction media proceeds faster than in saturated hydrocarbons, providing the formation of 1-hexene, 1-octene, and branched C10 and C12 olefins; the composition and the ratio of the reaction products depended on the nature of PNP ligand. Oligomerizates were used in ZN polymerization ‘as is’, without additional treatment. Due to branched character of C10+ hydrocarbons, formed during oligomerization of ethylene, resulting polyolefins demonstrate higher low-temperature DR efficiency at low polymer concentrations (~1 ppm) in comparison with benchmark polymers prepared from the mixtures of linear α-olefins and from pure 1-hexene. We assume that faster solubility and more efficient solvation of the polyolefins, prepared using ‘tandem’ ethylene-based process, represent an advantage of these type polymers over conventional poly(1-hexene) and linear α-olefin-based polymers when used as ‘winter’ DRAs.

Sol-Gel Synthesis of Organically Modified Silica Particles as Efficient Palladium Catalyst Supports to Perform Hydrogenation Process

Modern approaches to the production of new materials require the improvement of synthesis techniques towards simplifying the processes of their preparation and reducing the number of stages. Thus, in this study, one-stage synthesis of organomodified silica materials is developed using a special surfactant—dodecyldimethylamin N-oxide (DDAO). The peculiarity of this approach is that there is no need for heat treatment of the material, since DDAO is removed by washing in alcohol. Amino-, mercapto-, methyl-, and phenyl-modified silicas were synthesized using this method. The SEM images showed the morphology of all the obtained materials is close, all particles are spherical, and the diameter of individual particles is about 500 nm. Palladium particles were precipitated on these supports, then the experiments were carried out to study the catalytic activity of these materials in a model reaction of nitroaniline reduction. The phenyl modified matrix-based materials showed very low activity. This is due to the fact that the support and the substrate contain aromatic fragments, thus, hydrophobic interactions arise between them, which complicates the diffusion of the products. The leader is a matrix with an amino fragment, which is associated with its electron-donor effect. The XPS method revealed the amount of fixed palladium, as well as the binding energy shifts, which are 0.68 eV for 5% Pd/SiO2–C6H5; 0.56 eV for 5% Pd/SiO2–C3H6–NH2; 0.26 eV for 5% Pd/SiO2–CH3; and 0.13 eV for 5% Pd/SiO2.

One-stage synthesis of 1,1-diethoxyethane from ethanol using copper-containing catalysts

The conversion of ethanol on low-percentage copper-containing catalysts at temperatures of 300 oC and 350 oC was studied. γ-Al2O3, SiO2 and HZSM-5 were studied as the carrier of the active phase. It is shown that the main direction of ethanol conversion on low-percentage copper-containing catalysts is its dehydrogenation and subsequent conversion of the resulting products into 1,1-diethoxyethane. Among the studied catalysts (1 wt.% CuO/Al2O3, 1 wt.% CuO/SiO2 and 1 wt.% CuO/ HZSM-5 the most active in the production of 1,1-diethoxyethane was 1 wt.% CuO/Al2O3, modification of it with cerium oxide led to an increase in its activity in the formation of 1,1-diethoxyethane, at the reaction temperature of 350 oС, the yield of the target product was 27 vol.%. The results showed that the modification of CuO/Al2O3 leads to an increase in the catalytic activity of the sample.

PUSAT KOMUNITAS SEPEDA DI KOTA PONTIANAK

Bicycle is the sustainable land transport. The background of this design is the cycling trend in Pontianak City has existed since 2000. In 2005 the Bike to Work community was formed and until now more than 20 bicycle communities have been formed in Pontianak City. Members of the cycling community need a place to gather and share their interest in cycling, and people need a safe place to play and practice cycling. This design is in line with the commitment of the Pontianak City Government to realize Pontianak City as a bicycle-friendly city. The main purpose is to provide an interactive, flexible, and combine meeting point with the shape of bicycle wheels as part of the design. The design used the Whitaker design method, which consists of the introduction stage, definition stage, preparation stage, analysis stage, synthesis stage, evaluation stage, and re-evaluation stage. The main concept is to create eight bicycle community clusters that are integrated with commercial, recreational, and educational areas to meet the needs and lifestyles of cyclists. This design produces a plaza area with an arrangement of eight bicycle clusters that are centralized and integrated with a commercial area, waterfront, food court, and freestyle area with cluster organization.

SYNTHESIS OF 3,3´-(1,4-PHENYLENE)BIS(1-(4-R-PHENYL)-5-PHENYL-5,6-DIHYDRO-1,2,4,5-TETRAZINIUM) PERCHLORATES

A series of 3,3'-(1,4-phenylene)bis(1-4-R-phenyl)-5-phenyl-5,6-dihydro-1,2,4,5-tetrazinium) perchlorates containing hydrogen, methyl, bromio, methoxy, acetyl and nitro groups (R = H, Me, Br, OMe, COMe, NO2) as substituents were obtained as a result of a three-stage synthesis from terephthalic aldehyde. The synthesis of tetrazinium salts was carried out by reaction of the corresponding formazans with formalin in the presence of perchloric acid in dioxane. Formazans were obtained by reaction of terephthalic aldehyde phenylhydrazone with arenediazonium tosylates in a mixture of DMF and pyridine. The usage of arenediazonium tosylates made it possible to extremely simplify the segregation and purification of formazans. The phenylhydrazone was synthesized according to the standard procedure from terephthalic aldehyde and phenylhydrazine/hydrochloric acid in aqueous dioxane. The formazans and tetrazinium perchlorates were isolated in individual state and characterized by elemental analysis, IR, UV, 1H and 13C NMR spectroscopy data. The process of electrochemical reduction of tetrazinium perchlorates was studied using the method of cyclic voltammetry (CV). Thus, the CV curves of all salts in the cathode region contain two one-electron reduction peaks, which are related to the sequential formation of a radical cation and a biradical. It was found that electron-donating substituents (R = Me, OMe) in the aromatic ring at position 1 facilitate the reduction of tetrazinium cation, while electron-withdrawing substituents (R = COMe, NO2) hinder this process. On this basis, it was suggested that the corresponding bis-verdazyl radicals should be easily formed in the presence of electron-donating substituents in the aromatic ring at position 1. Thus, 3,3´-(1,4-phenylene)bis(1-(4-R-phenyl)-5-phenyl-5,6-dihydro-1,2,4,5-tetrazinium-1) perchlorates are perspective precursors of symmetric biradical systems based on verdazyl radicals.

Step-by-step analytical synthesis of the mathematical model of automotive unmanned aircraft

The problem of the stage-by-stage synthesis of the mathematical model of the autopilot of an unmanned aerial vehicle (UAV) is considered. At the first stage, an analytical synthesis of the control acceleration applied to the center of mass of the UAV is performed to form a specified trajectory of its flight. On the basis of the results received at the first stage, at the subsequent stages, the problem of synthesizing a mathematical model of the UAV autopilot is solved with the specified requirements for ensuring the stability and dynamic accuracy of UAV control. Under actual assumptions about the corresponding nature of changes in the trajectory parameters and variables that characterize the motion of the UAV in space, the use of a linear mathematical model of the evolution of the state vector of the UAV and its control system is substantiated. When synthesizing a mathematical model of the UAV autopilot, the method of modal control of the system was used for a specified mathematical model of the object. For a specified model of motion and aerodynamic characteristics of the UAV, the law of deviation of the control steering surface is analytically received, which depends on the parameters of the translational and rotational movement of the UAV. Computer simulation of the analytically received results of control synthesis for the specified characteristics of UAVs and specific using conditions was carried out, which clearly showed the efficiency and prospects of using this approach for the synthesis of control systems for UAVs of various purposes and design.

Highly Fluorinated Trianglimine Macrocycles: A Supramolecular Organic Framework

A novel highly fluorinated dialdehyde was prepared by a two-stage synthesis. This reactive building block for dynamic imine chemistry was used in a condensation reaction to generate the first extensively fluorinated trianglimine. An analysis of the material properties and, especially, the crystal structure of the [3+3] macrocycle revealed a supramolecular organic framework with tubular porous channels. The use of fluorinated ligands to generate hydrophobic electron-deficient channel-like pores is an important addition to the ever-expanding field of supramolecular networks and to trianglimine chemistry in general.