Enantioselective phase transfer alkylation using orthopalladated complex in chiral ionic liquid

2008 ◽  
Vol 9 (1) ◽  
pp. 40-44 ◽  
Author(s):  
Deb Kumar Mukherjee ◽  
Nripendranath Ghosh
Keyword(s):  
Ionic Liquid ◽  
Phase Transfer ◽  
Chiral Ionic Liquid

scholarly journals A novel thermoregulated phase-transfer catalysis system for chiral nano-Pt-catalyzed asymmetric hydrogenation

2021 ◽  
pp. 174751982110391
Author(s):  
Pu Chen ◽  
Yanhua Wang
Keyword(s):  
Ionic Liquid ◽  
Cloud Point ◽  
Phase Transfer Catalysis ◽  
Phase Transfer ◽  
Enantiomeric Excess ◽  
Asymmetric Hydrogenation ◽  
Biphasic System ◽  
Pt Catalyst ◽  
Chiral Ionic Liquid ◽  
Pt Catalyzed

The chiral ionic liquid CILTPT-MS [CH3(OCH2CH2)16CD]+[CH3SO3]− (CD = cinchonidine) is found to exhibit cloud point character. Due to this cloud point character, a CILTPT-MS-stabilized chiral nano-Pt catalyst is prepared and utilized to realize transfer in a H2O–1-pentanol biphasic system by simply changing the temperature. Therefore, a fluorine-free, thermoregulated phase-transfer catalysis system is developed and applied to the asymmetric hydrogenation of α-ketoesters with enantiomeric excess of >99% and excellent conversion. In addition, the chiral nano-Pt catalyst can be easily separated and reused efficiently.

ChemInform Abstract: Chiral Ionic Liquid Mediated Diels-Alder Reaction Between Anthrone Enolate and Maleimides.

ChemInform ◽  
2010 ◽  
Vol 41 (40) ◽  
pp. no-no
Author(s):  
Nitin A. Mirgane ◽  
Mohammed Hasan H. Akhtar ◽  
Anil V. Karnik
Keyword(s):  
Ionic Liquid ◽  
Alder Reaction ◽  
Diels Alder ◽  
Diels Alder Reaction ◽  
Chiral Ionic Liquid

Synthesis and Characterization of N-butyl-N-methylimidazolium- D-(-)-tartrate Chiral Ionic Liquid

2012 ◽  
Vol 518-523 ◽  
pp. 3989-3992 ◽  
Author(s):  
Yang Zhang ◽  
Xiao Hua Tu ◽  
Cheng Ping Miao ◽  
Jian Yi Wu
Keyword(s):  
Ionic Liquid ◽  
1H Nmr ◽  
Ion Chromatography ◽  
13C Nmr ◽  
Nmr Spectra ◽  
Optical Rotation ◽  
Synthesis And Characterization ◽  
13C Nmr Spectra ◽  
Chiral Ionic Liquid

A novel CIL of N-butyl-N-methyl imidazolium-D-(-)-tartrate has been designed and synthesized by neutralization reaction. Its structure was characterized by 1H-NMR and 13C-NMR spectra, the optical rotation was characterized by polarimeter with the value of-15.0º, and the purity was characterized by ion chromatography with the value of 98.4%.

Ionic Liquid-Responsive Phase Transfer of Gold Nanoparticles: Anionic Metathesis

Langmuir ◽  
2019 ◽  
Vol 35 (28) ◽  
pp. 9213-9218 ◽  
Author(s):  
Sachin Thawarkar ◽  
Trupti C. Nirmale ◽  
Sahebrao More ◽  
Jalindar D. Ambekar ◽  
Bharat B. Kale ◽  
...  
Keyword(s):  
Gold Nanoparticles ◽  
Ionic Liquid ◽  
Phase Transfer

scholarly journals Chiral ionic liquid crystals based on thiourea

2019 ◽  
Vol 43 (5) ◽  
pp. 2053-2056 ◽  
Author(s):  
Sarah Kirchhecker ◽  
Duncan W. Bruce
Keyword(s):  
Ionic Liquid ◽  
Liquid Crystals ◽  
Ionic Liquid Crystals ◽  
Chiral Ionic Liquid

Chiral ionic liquid crystals based on the S-methyl-N,N′-α-methylarylthiouronium cation have been prepared and studied.

scholarly journals Combined use of chiral ionic liquid and CD for MEKC: Part II. Determination of binding constants

2009 ◽  
Vol 30 (16) ◽  
pp. 2820-2828 ◽  
Author(s):  
Bin Wang ◽  
Jun He ◽  
Victoria Bianchi ◽  
Shahab A. Shamsi
Keyword(s):  
Ionic Liquid ◽  
Binding Constants ◽  
Combined Use ◽  
Chiral Ionic Liquid
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