Synthesis, Crystal structure and thermal reactivity of [(N2H5)2Mn0.20Ni0.80(C2O4)2](H2O)2: A novel precursor to nickel-manganese oxide

2021 ◽  
pp. 100784
Author(s):  
R. Pradeep ◽  
B.N. Sivasankar
2010 ◽  
Vol 12 (11) ◽  
pp. 1618-1621 ◽  
Author(s):  
Donghan Kim ◽  
Sun-Ho Kang ◽  
Mahalingam Balasubramanian ◽  
Christopher S. Johnson

Author(s):  
Matthias Weil ◽  
Théo Veyer

A new form of NaMnAsO4, sodium manganese(II) orthoarsenate, has been obtained under hydrothermal conditions, and is referred to as the β-polymorph. In contrast to the previously reported orthorhombic α-polymorph that crystallizes in the olivine-type of structure and has one manganese(II) cation in a distorted octahedral coordination, the current β-polymorph contains two manganese(II) cations in [5]-coordination, intermediate between a square-pyramid and a trigonal bipyramid. In the crystal structure of β-NaMnAsO4, four [MnO5] polyhedra are linked through vertex- and edge-sharing into finite {Mn4O16} units strung into rows parallel to [100]. These units are linked through two distinct orthoarsenate groups into a framework structure with channels propagating parallel to the manganese oxide rows. Both unique sodium cations are situated inside the channels and exhibit coordination numbers of six and seven. β-NaMnAsO4 is isotypic with one form of NaCoPO4 and with NaCuAsO4.


2020 ◽  
Vol 7 (2) ◽  
pp. 561-568 ◽  
Author(s):  
Roopathy Mohan ◽  
Arindam Modak ◽  
Palaniappan Subramanian ◽  
Rivka Cahan ◽  
P. Sivakumar ◽  
...  

2016 ◽  
Vol 8 (19) ◽  
pp. 12176-12185 ◽  
Author(s):  
Sivakumar Periyasamy ◽  
Palaniappan Subramanian ◽  
Elena Levi ◽  
Doron Aurbach ◽  
Aharon Gedanken ◽  
...  

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