Potentiostatic and impedance spectroscopic studies of the anodic behavior of cobalt silicides in fluoride-containing acidic solutions

2019 ◽  
Vol 159 ◽  
pp. 108124 ◽  
Author(s):  
V.I. Kichigin ◽  
A.B. Shein
1982 ◽  
Vol 36 (4) ◽  
pp. 436-440 ◽  
Author(s):  
D. S. Kendall ◽  
D. E. Leyden ◽  
L. W. Burggraf ◽  
F. J. Pern

Infrared and photoacoustic spectroscopies have in combination produced useful information about an immobilized β-diketone, formed by the reaction of acetylacetone with p-chloromethylphenyltrimethoxysilane previously immobilized on silica. Evidence confirming the synthesis of immobilized 3-benzyl-2,4-pentanedione is presented. Comparisons with 3-benzyl-2,4-pentanedione, a model for the surface bonded ligand, were valuable. The bound β-diketone is largely in the keto tautomer on the surface. The photoacoustic spectrum shows that the remainder is in the form of an intermolecular hydrogen-bonded enol. In basic solution the enolate ion and metal-enolate complexes can be formed. Infrared spectra show that the keto form can bind metals in acidic solutions.


1987 ◽  
Vol 84 ◽  
pp. 443-448 ◽  
Author(s):  
Teresa Kowalik ◽  
Brigitte Decock-Le Reverend ◽  
Claude Loucheux ◽  
Damien Ficheux ◽  
Henryk Kozlowski

1980 ◽  
Vol 41 (C1) ◽  
pp. C1-187-C1-188 ◽  
Author(s):  
G. P. Gupta ◽  
J. A. Baines ◽  
D. M. Cooper ◽  
D. P.E. Dickson ◽  
C. E. Johnson

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