Reactions of olefin derivatives in the presence of metathesis catalysts

2021 ◽  
Vol 2021 (12) ◽  
pp. 7
Keyword(s):  
Metathesis Catalysts

Activated Hoveyda‐Grubbs Olefin Metathesis Catalysts Derived from a Large Scale Produced Pharmaceutical Intermediate—Sildenafil Aldehyde

2021 ◽  
Author(s):  
Louis Monsigny ◽  
Jakub Piątkowski ◽  
Damian Trzybiński ◽  
Krzysztof Wozniak ◽  
Tomasz Nienałtowski ◽  
...  
Keyword(s):  
Olefin Metathesis ◽  
Large Scale ◽  
Metathesis Catalysts

scholarly journals A General Decomposition Pathway for Phosphine-Stabilized Metathesis Catalysts: Lewis Donors Accelerate Methylidene Abstraction

2016 ◽  
Vol 138 (44) ◽  
pp. 14668-14677 ◽  
Author(s):  
William L. McClennan ◽  
Stephanie A. Rufh ◽  
Justin A. M. Lummiss ◽  
Deryn E. Fogg
Keyword(s):  
Metathesis Catalysts ◽  
Decomposition Pathway

Nitrenium ions and trivalent boron ligands as analogues of N-heterocyclic carbenes in olefin metathesis: a computational study

2015 ◽  
Vol 44 (46) ◽  
pp. 20021-20026 ◽  
Author(s):  
A. Pazio ◽  
K. Woźniak ◽  
K. Grela ◽  
B. Trzaskowski
Keyword(s):  
Olefin Metathesis ◽  
Computational Study ◽  
Heterocyclic Carbenes ◽  
Mechanistic Study ◽  
Nitrenium Ions ◽  
Nitrenium Ion ◽  
Metathesis Catalysts

A DFT mechanistic study reveals that nitrenium ion-modified Hoveyda-like complexes are good candidates for latent metathesis catalysts, while boron-modified systems are candidates for very fast metathesis catalysts.

Adamantyl-SubstitutedN-Heterocyclic Carbene Ligands in Second-Generation Grubbs-Type Metathesis Catalysts

2003 ◽  
Vol 22 (25) ◽  
pp. 5291-5296 ◽  
Author(s):  
Maarten B. Dinger ◽  
Piotr Nieczypor ◽  
Johannes C. Mol
Keyword(s):  
Second Generation ◽  
Carbene Ligands ◽  
Metathesis Catalysts

scholarly journals Impact of Ligands and Metals on the Formation of Metallacyclic Intermediates and a Nontraditional Mechanism for Group VI Alkyne Metathesis Catalysts

2021 ◽  
Author(s):  
Richard R. Thompson ◽  
Madeline E. Rotella ◽  
Xin Zhou ◽  
Frank R. Fronczek ◽  
Osvaldo Gutierrez ◽  
...  
Keyword(s):  
Alkyne Metathesis ◽  
Group Vi ◽  
Metathesis Catalysts

Cyclometalated Z-Selective Ruthenium Metathesis Catalysts with Modified N-Chelating Groups

2015 ◽  
Vol 34 (12) ◽  
pp. 2858-2869 ◽  
Author(s):  
Myles B. Herbert ◽  
Benjamin A. Suslick ◽  
Peng Liu ◽  
Lufeng Zou ◽  
Peter K. Dornan ◽  
...  
Keyword(s):  
Metathesis Catalysts ◽  
Chelating Groups
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