Synthesis of Water-Soluble, Aliphatic Phosphines and Their Application to Well-Defined Ruthenium Olefin Metathesis Catalysts

1996 ◽  
Vol 15 (20) ◽  
pp. 4317-4325 ◽  
Author(s):  
Bernhard Mohr ◽  
David M. Lynn ◽  
Robert H. Grubbs
Keyword(s):  
Olefin Metathesis ◽  
Water Soluble ◽  
Metathesis Catalysts

Activated Hoveyda‐Grubbs Olefin Metathesis Catalysts Derived from a Large Scale Produced Pharmaceutical Intermediate—Sildenafil Aldehyde

2021 ◽  
Author(s):  
Louis Monsigny ◽  
Jakub Piątkowski ◽  
Damian Trzybiński ◽  
Krzysztof Wozniak ◽  
Tomasz Nienałtowski ◽  
...  
Keyword(s):  
Olefin Metathesis ◽  
Large Scale ◽  
Metathesis Catalysts

Nitrenium ions and trivalent boron ligands as analogues of N-heterocyclic carbenes in olefin metathesis: a computational study

2015 ◽  
Vol 44 (46) ◽  
pp. 20021-20026 ◽  
Author(s):  
A. Pazio ◽  
K. Woźniak ◽  
K. Grela ◽  
B. Trzaskowski
Keyword(s):  
Olefin Metathesis ◽  
Computational Study ◽  
Heterocyclic Carbenes ◽  
Mechanistic Study ◽  
Nitrenium Ions ◽  
Nitrenium Ion ◽  
Metathesis Catalysts

A DFT mechanistic study reveals that nitrenium ion-modified Hoveyda-like complexes are good candidates for latent metathesis catalysts, while boron-modified systems are candidates for very fast metathesis catalysts.

Ruthenium Olefin Metathesis Catalysts with Modified Styrene Ethers: Influence of Steric and Electronic Effects.

ChemInform ◽  
2003 ◽  
Vol 34 (49) ◽  
Author(s):  
Mirko Zaja ◽  
Stephen J. Connon ◽  
Aideen M. Dunne ◽  
Michael Rivard ◽  
Nicole Buschmann ◽  
...  
Keyword(s):  
Olefin Metathesis ◽  
Electronic Effects ◽  
Metathesis Catalysts
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