Metal-organic framework containing Brønsted acidity and Lewis acidity for efficient conversion glucose to levulinic acid

2019 ◽  
Vol 193 ◽  
pp. 1-6 ◽  
Author(s):  
Haonan Qu ◽  
Bingyi Liu ◽  
Guohua Gao ◽  
Yiming Ma ◽  
Yanmei Zhou ◽  
...  
Keyword(s):  
Levulinic Acid ◽  
Metal Organic Framework ◽  
Lewis Acidity ◽  
Brønsted Acidity ◽  
Efficient Conversion ◽  
Brönsted Acidity ◽  
Metal Organic ◽  
Organic Framework

scholarly journals Unexpected linker-dependent Brønsted acidity in the (Zr)UiO-66 metal organic framework and application to biomass valorization

2020 ◽  
Vol 10 (12) ◽  
pp. 4002-4009 ◽  
Author(s):  
Guangxia Fu ◽  
Francisco G. Cirujano ◽  
Andraž Krajnc ◽  
Gregor Mali ◽  
Mickaël Henrion ◽  
...  
Keyword(s):  
Metal Organic Framework ◽  
Brønsted Acidity ◽  
Biomass Valorization ◽  
Brönsted Acidity ◽  
Metal Organic ◽  
Organic Framework

The functionality of the UiO-66(Zr) linkers affects the number of defects on the Zr6 clusters, leading to differences in the MOFs' Brønsted acidity, which promotes the dehydration of fructose into HMF.

Ruthenium Complexes Immobilized on an Azolium Based Metal Organic Framework for Highly Efficient Conversion of CO2 into Formic Acid

ChemCatChem ◽  
2019 ◽  
Vol 11 (4) ◽  
pp. 1256-1263 ◽  
Author(s):  
Chao Wu ◽  
Faisal Irshad ◽  
Maowei Luo ◽  
Yujun Zhao ◽  
Xinbin Ma ◽  
...  
Keyword(s):  
Formic Acid ◽  
Metal Organic Framework ◽  
Ruthenium Complexes ◽  
Efficient Conversion ◽  
Highly Efficient ◽  
Metal Organic ◽  
Organic Framework

A tri-functional metal–organic framework heterogeneous catalyst for efficient conversion of CO2 under mild and co-catalyst free conditions

2019 ◽  
Vol 55 (95) ◽  
pp. 14347-14350 ◽  
Author(s):  
Dingxuan Ma ◽  
Yaowen Zhang ◽  
Shaoshao Jiao ◽  
Jixin Li ◽  
Kang Liu ◽  
...  
Keyword(s):  
Synergistic Effect ◽  
Heterogeneous Catalyst ◽  
Lewis Acid ◽  
Metal Organic Framework ◽  
Catalytic Performance ◽  
Co Catalyst ◽  
Efficient Conversion ◽  
Catalyst Free ◽  
Metal Organic ◽  
Organic Framework

A novel tri-functional MOF catalyst was achieved by PSM method. Because of the synergistic effect of Lewis acid, Brønsted acid and Br− anion, MIL-IMAc-Br− displayed an efficient catalytic performance for CO2 conversion.

scholarly journals MIL-100(Fe)-catalyzed efficient conversion of hexoses to lactic acid

RSC Advances ◽  
2017 ◽  
Vol 7 (10) ◽  
pp. 5621-5627 ◽  
Author(s):  
Shan Huang ◽  
Kai-Li Yang ◽  
Xiao-Fang Liu ◽  
Hu Pan ◽  
Heng Zhang ◽  
...  
Keyword(s):  
Lactic Acid ◽  
Metal Organic Framework ◽  
Catalytic Transformation ◽  
Efficient Conversion ◽  
Hexose Sugars ◽  
Metal Organic ◽  
First Time ◽  
Organic Framework

Lewis acidic metal–organic framework (MOF), MIL-100(Fe), was for the first time demonstrated to be efficient for the catalytic transformation of hexose sugars into lactic acid.

scholarly journals Probing the Lewis Acidity and Catalytic Activity of the Metal–Organic Framework [Cu3(btc)2] (BTC=Benzene-1,3,5-tricarboxylate)

2006 ◽  
Vol 12 (28) ◽  
pp. 7353-7363 ◽  
Author(s):  
Luc Alaerts ◽  
Etienne Séguin ◽  
Hilde Poelman ◽  
Frédéric Thibault-Starzyk ◽  
Pierre A. Jacobs ◽  
...  
Keyword(s):  
Catalytic Activity ◽  
Metal Organic Framework ◽  
Lewis Acidity ◽  
Metal Organic ◽  
Organic Framework
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