Organic–inorganic hybrid coordination polymers based on tetratopic pyridyl-bridging ligand: Syntheses, structures, and luminescent properties

A novel bridging asymmetric benzimidazole ligand, 4-{2-[3-(pyridin-4-yl)phenyl]-1H-benzimidazol-1-ylmethyl}benzoic acid, was used to construct three isomorphous two-dimensional coordination polymers, namelycatena-poly[chlorido(μ3-4-{2-[3-(pyridin-4-yl)phenyl]-1H-benzimidazol-1-ylmethyl}benzoato)zinc(II)], [Zn(C26H18N3O2)Cl]n, (I), and the bromide, (II), and iodide, (III), analogues. Neighbouring two-dimensional networks are stacked into three-dimensional frameworksviainterlayer π–π interactions. The luminescent properties of (I)–(III) were investigated and they display an obvious red-shift in the solid state at room temperature.

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Two- to One-Dimensional: Radii-Dependent Self-Assembly Crystal Structures and Luminescent Properties of Lanthanide Coordination Polymers with an Amide Type Semirigid Bridging Ligand

Crystal Growth & Design ◽

10.1021/cg200816f ◽

2011 ◽

Vol 11 (9) ◽

pp. 4205-4212 ◽

Cited By ~ 41

Author(s):

Xuhuan Yan ◽

Yafei Li ◽

Qiong Wang ◽

Xiaoguang Huang ◽

Ye Zhang ◽

...

Keyword(s):

Crystal Structures ◽

Coordination Polymers ◽

Self Assembly ◽

Luminescent Properties ◽

One Dimensional ◽

Lanthanide Coordination Polymers ◽

Bridging Ligand

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Assembly of four d10-metal inorganic–organic hybrid coordination polymers based on bipyrazine imine-based ligand: Synthesis, crystal structures and luminescent properties

CrystEngComm ◽

10.1039/c1ce06030a ◽

2012 ◽

Vol 14 (5) ◽

pp. 1575-1581 ◽

Cited By ~ 23

Author(s):

Yan Bai ◽

Jun-Li Wang ◽

Dong-Bin Dang ◽

Meng-Meng Li ◽

Jing-Yang Niu

Keyword(s):

Crystal Structures ◽

Coordination Polymers ◽

Luminescent Properties ◽

Organic Hybrid ◽

D10 Metal ◽

Ligand Synthesis ◽

Hybrid Coordination

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Ethylenediamine as a bridging ligand: structure solution of two cadmium(II)-based coordination polymers from powder diffraction data

Powder Diffraction ◽

10.1017/s0885715613000146 ◽

2013 ◽

Vol 28 (3) ◽

pp. 207-211 ◽

Cited By ~ 2

Author(s):

Piotr Putaj ◽

Bartłomiej Gaweł ◽

Wiesław Łasocha

Keyword(s):

Powder Diffraction ◽

Coordination Polymers ◽

Diffraction Data ◽

Direct Methods ◽

Powder Diffraction Data ◽

Metal Centers ◽

Space Group ◽

Bridging Ligand ◽

Structure Solution ◽

Hybrid Coordination

Structures of [Cd(C2H8N2)Cl2]n(1) and [Cd(C2H8N2)Br2]n(2) were solved from powder diffraction data. Compound (1) crystallizes in the space group Pbam (No. 55), a = 9.9021(7) Å, b = 7.8186(6) Å, c = 4.0705(3) Å, V = 315.13(3) Å3, Z = 2. (2) is isostructural: space group Pbam (No. 55), a = 10.405(2) Å, b = 7.8634(8) Å, c = 4.2079(5) Å, V = 344.28(6) Å3, Z = 2. The investigated compounds are examples of two-dimensional hybrid coordination polymers, in which neighboring metal centers are bridged via both organic and inorganic moieties: ethylenediamine molecules and halide anions. Both crystal structures were solved ab initio from powder data using direct methods.

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One-dimensional coordination polymers generated from a new triazole bridging ligand and HgX2(X= Cl, Br and I): characterization and luminescent properties

Acta Crystallographica Section C Crystal Structure Communications ◽

10.1107/s0108270112017659 ◽

2012 ◽

Vol 68 (6) ◽

pp. m147-m151 ◽

Cited By ~ 1

Author(s):

Na Qin ◽

Chao-Wei Zhao ◽

Jian-Ping Ma ◽

Qi-Kui Liu ◽

Yu-Bin Dong

Keyword(s):

Coordination Polymers ◽

Three Dimensional ◽

Luminescent Properties ◽

Coordination Complexes ◽

The Other ◽

Tridentate Ligand ◽

Dimensional Structure ◽

One Dimensional ◽

Bridging Ligand ◽

Solvent Molecules

The new 4-amino-1,2,4-triazole asymmetric bridging ligand 4-amino-5-(pyridin-3-yl)-3-[4-(pyridin-4-yl)phenyl]-4H-1,2,4-triazole (L) has been used to generate three novel isomorphic one-dimensional coordination polymers,viz. catena-poly[[tris[dichloridomercury(II)]-bis{μ3-4-amino-5-(pyridin-3-yl)-3-[4-(pyridin-4-yl)phenyl]-4H-1,2,4-triazole}] acetonitrile monosolvate], {[Hg3Cl6(C18H14N6)2]·CH3CN}n, (I), and the bromido, {[Hg3Br6(C18H14N6)2]·CH3CN}n, (II), and iodido, {[Hg3I6(C18H14N6)2]·CH3CN}n, (III), analogs. The asymmetric ligand acts as a tridentate ligand to coordinate the three different HgIIcenters (two of which are symmetry-related). Two ligands and two symmetry-related HgIIcenters form centrosymmetric rectangular units which are linked into one-dimensional chainsviathe other unique Hg atoms, which sit on mirror planes. The chains are elaborated into a three-dimensional structureviainterchain hydrogen bonds. The acetonitrile solvent molecules are located in ellipsoidal cavities. The luminescent character of these three coordination complexes was investigated in the solid state.

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